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Enhancement of photocatalytic decomposition of perfluorooctanoic acid on CeO2/In2O3

机译:CEO2 / IN2O3中全氟辛酸光催化分解的增强

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摘要

CeO2-doped indium oxide photocatalysts (xCeO(2)/In2O3) with various CeO2 doping amounts were synthesized and systematically characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis spectra, photoluminescence spectroscopy (PL) and photocurrent measurements. The as-obtained xCeO(2)/In2O3 photocatalysts were used in photocatalytic degradation of PFOA for the first time and much higher photocatalytic activity of xCeO(2)/In2O3 than CeO2 and In2O3 was obtained under UV light irradiation. The excellent photocatalytic activity of 0.86% CeO2/In2O3 could be mainly derived from effective inhibition of recombination of photo-induced electron-holes caused by the charge transfer between CeO2 and In2O3. Moreover, the 0.86% CeO2/In2O3 catalyst showed excellent photocatalytic stability in cycling runs for the photocatalytic degradation of PFOA, providing a great potential of CeO2/In2O3 catalysts for PFOA treatment.
机译:通过X射线粉末衍射(XRD),透射电子显微镜(TEM),X射线光电子体谱(XPS)合成和系统以各种CeO2掺杂量合成和系统地进行了各种CeO2掺杂量的CeO2掺杂氧化物光催化剂(Xceo(2)/ In2O3)。 UV-Vis光谱,光致发光光谱(PL)和光电流测量。 在PFOA的光催化降解的AS-LaveO(2)/ In2O3光催化剂中首次和XCEO(2)/ In2O3的光催化活性比CEO2和IN2O3在UV光照射下获得的光催化活性。 优异的光催化活性为0.86%CeO 2 / In2O3主要可以产生由CeO2和In2O3之间的电荷转移引起的光诱导电子 - 孔的重组的有效抑制。 此外,0.86%CeO 2 / In2O3催化剂在循环过程中显示出优异的光催化稳定性,用于PFOA的光催化降解,提供CeO2 / In2O3催化剂的潜力,用于PFOA处理。

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  • 来源
    《RSC Advances》 |2016年第76期|共7页
  • 作者单位

    Nanjing Univ Sci &

    Technol Sch Environm &

    Biol Engn Key Lab Jiangsu Prov Chem Pollut Control &

    Resour Nanjing 210094 Jiangsu Peoples R China;

    Nanjing Univ Sci &

    Technol Sch Environm &

    Biol Engn Key Lab Jiangsu Prov Chem Pollut Control &

    Resour Nanjing 210094 Jiangsu Peoples R China;

    Nanjing Univ Sci &

    Technol Sch Environm &

    Biol Engn Key Lab Jiangsu Prov Chem Pollut Control &

    Resour Nanjing 210094 Jiangsu Peoples R China;

    Nanjing Univ Sci &

    Technol Sch Environm &

    Biol Engn Key Lab Jiangsu Prov Chem Pollut Control &

    Resour Nanjing 210094 Jiangsu Peoples R China;

    Yancheng Teachers Coll Jiangsu Prov Key Lab Coastal Wetland Bioresources Yancheng 224002 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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