Can chiral P(III) coordinate Eu(III)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(III)(hfa)(3) in chloroform and acetone

Kono Yuki; Nakabayashi Kazuki; Kitamura Sayaka; Shizuma Motohiro; Fujiki Michiya; Imai Yoshitane

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Can chiral P(III) coordinate Eu(III)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(III)(hfa)(3) in chloroform and acetone

机译：可以手表p（iii）坐标欧盟（iii）？在氯仿和丙酮中，Binap和Eu（III）（HFA）（3）（HFA）（3）的意外溶剂依赖性圆极化发光

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The coordination of Eu(III) (from Eu(III)(hfa)(3)) by chiral P(III) (from BINAP) led to circularly polarised luminescence in dilute solutions on the order of vertical bar g(em)vertical bar approximate to 10(-2) at D-5(0) -> F-7(1) and vertical bar g(em)vertical bar approximate to 10(-3) at D-5(0) -> F-7(2) transitions regardless of the coordinating ability of the solvent (i.e., in non-coordinating ethanol-free chloroform and coordinating acetone).

机译：通过手性P（III）（来自BINAP）的欧盟（III）（来自欧盟（III）（HFA）（3））的协调导致垂直条G（EM）垂直条的稀释溶液中的圆偏振发光。在D-5（0） - > F-7（1）和垂直条G（EM）垂直条的近似为10（-3）近似为10（0） - > F-7 （2）无论溶剂的配位能力如何（即，在非协调的乙醇 - 无氯仿和协调丙酮中）。

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来源
《RSC Advances》 |2016年第46期|共6页
作者
Kono Yuki; Nakabayashi Kazuki; Kitamura Sayaka; Shizuma Motohiro; Fujiki Michiya; Imai Yoshitane;
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作者单位

Kindai Univ Fac Sci &

Engn Dept Appl Chem 3-4-1 Kowakae Osaka 5778502 Japan;

Kindai Univ Fac Sci &

Engn Dept Appl Chem 3-4-1 Kowakae Osaka 5778502 Japan;

Kindai Univ Fac Sci &

Engn Dept Appl Chem 3-4-1 Kowakae Osaka 5778502 Japan;

Osaka Municipal Tech Res Inst Dept Biochem Joto Ku 1-6-50 Morinomiya Osaka 5368553 Japan;

Nara Inst Sci &

Technol Grad Sch Mat Sci Nara 6300192 Japan;

Kindai Univ Fac Sci &

Engn Dept Appl Chem 3-4-1 Kowakae Osaka 5778502 Japan;

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1. Can chiral P(III) coordinate Eu(III)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(III)(hfa)(3) in chloroform and acetone [J] . Kono Yuki, Nakabayashi Kazuki, Kitamura Sayaka, RSC Advances . 2016,第46期

机译：可以手表p（iii）坐标欧盟（iii）？在氯仿和丙酮中，Binap和Eu（III）（HFA）（3）（HFA）（3）的意外溶剂依赖性圆极化发光
2. Circularly polarised luminescence from planar-chiral Phanephos/Tb(III)(hfa)(3) hybrid luminophores [J] . Taniguchi Ayano, Hara Nobuyuki, Shizuma Motohiro, Photochemical & photobiological sciences: the official journal of the European Photochemistry Association and the European Society for Photobiology . 2019,第12期

机译：来自平面手性肺鱼/ Tb（III）（HFA）（3）杂交发光体的圆偏振发光
3. Chiral probe development for circularly polarised luminescence: comparative study of structural factors determining the degree of induced CPL with four heptacoordinate europium(III) complexes [J] . Neil Emily R., Fox Mark A., Pal Robert, Dalton transactions: An international journal of inorganic chemistry . 2015,第33期

机译：圆极化发光的手性探针开发：结构因素的比较研究确定四种七配位euro（III）配合物诱导CPL的程度
4. Circularly polarized luminescence of a chiral Eu(III) complex depending on solvents [C] . Satoshi Wada, Yuichi Kitagawa, Takayuki Nakanishi 日本化学会春季年会講演予稿集 . 2018

机译：根据溶剂的手性欧盟（III）复合物的圆偏振发光
5. Selective activation of terbium(III) and europium(III) luminescencewith triarylboron-functionnalized carboxylate ligands. And Luminescent 8-hydroxyquinoline dipicolylamine complexes as sensors for zinc(II) [D] . Varlan, Maria. 2012

机译：用三芳基硼官能化的羧酸盐配体选择性激活activation（III）和euro（III）发光。发光的8-羟基喹啉二聚烯丙基胺配合物作为锌（II）的传感器
6. Chiroptical spectra of a series of tetrakis((+)–3–heptafluorobutylyrylcamphorato)lanthanide(III) with an encapsulated alkali metal ion: circularly polarized luminescence and absolute chiral structures for the Eu(III) and Sm(III) complexes [O] . Jamie L. Lunkley, Dai Shirotani, Kazuaki Yamanari, -1

机译：圆偏振的发光和绝对手性结构的铕（III）和sm（III）络合物：封装有碱金属离子的镧系元素（III） - 一系列四（3- heptafluorobutylyrylcamphorato（+））的手性光学的光谱
7. Chiral probe development for circularly polarised luminescence : comparative study of structural factors determining the degree of induced CPL with four heptacoordinate europium(III) complexes. [O] . Neil E.R., Fox M.A., Pal R., 2015

机译：圆极化发光的手性探针的发展：结构因素的比较研究确定与四个七配位euro（III）配合物诱导CPL的程度。

Can chiral P(III) coordinate Eu(III)? Unexpected solvent dependent circularly polarised luminescence of BINAP and Eu(III)(hfa)(3) in chloroform and acetone

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