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Hydrophilic modification of PVDF porous membrane via a simple dip-coating method in plant tannin solution

机译:植物单宁溶液中简单浸涂法亲水改性PVDF多孔膜

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摘要

To improve the hydrophilicity of polyvinylidene fluoride (PVDF) porous membranes, herein, we report for the first time a low-cost and environmental plant tannin coating, which is strongly constructed on the surface of the PVDF membrane via a simple dip-coating method. An oxidation induced aggregation mechanism was detected in the tannin solution through the use of ultraviolet spectrophotometry (UV-Vis). The morphology and chemical composition of the tannin coated PVDF membrane were characterized via field-emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS) and attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR). After coating with the tannin coating, hydrophilicity and filtration performance are both greatly enhanced, and the modified membranes also have a good emulsion separation performance and excellent antifouling property (after emulsion separation, the flux recovery ratio even reaches 100%). Moreover, these membranes possess outstanding durability that is disclosed by a long-term rinsing experiment. These results indicate that the plant tannin coating has great potential application for the hydrophilic modification of hydrophobic membranes.
机译:为了改善聚偏二氟乙烯(PVDF)多孔膜的亲水性,在此,我们首次报告低成本和环境植物单宁涂层,其通过简单的浸涂方法在PVDF膜的表面上强烈地构造。通过使用紫外分光光度法(UV-VI)在单宁溶液中检测氧化诱导的聚集机制。通过现场 - 发射扫描电子显微镜(FeSEM),X射线光电子能谱(XPS),并衰减总反射率傅里叶变换红外光谱(ATR-FTIR)的形态和化学成分的表征特征在于丹宁涂覆的PVDF膜。在用单宁涂层涂覆后,亲水性和过滤性能大大提高,改性膜还具有良好的乳液分离性能和优异的防污性(乳液分离后,助焊剂恢复比甚至达到100%)。此外,这些膜具有优异的耐久性,该实验是由长期漂洗实验公开的。这些结果表明,植物单宁涂层具有很大的潜在应用,用于疏水性膜的亲水性改性。

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  • 来源
    《RSC Advances》 |2016年第75期|共8页
  • 作者单位

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

    Wuhan Univ Technol Sch Mat Sci &

    Engn Wuhan 430070 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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