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Enhanced photovoltaic performance with co-sensitization of a ruthenium(II) sensitizer and an organic dye in dye-sensitized solar cells

机译:增强了光伏性能,具有钌(II)敏化剂的共敏化和染料敏化太阳能电池中的有机染料的共敏化

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摘要

Co-sensitization is demonstrated to be an effective technique to enhance the efficiency of dye-sensitized solar cells, where an efficiency of 9.23% is achieved by mixing N3 and RK-1 dyes. The assembled solar cells are characterized by UV-vis absorption measurements, current-voltage characteristics, and electrochemical impedance spectroscopy. The co-sensitized solar cell shows an enhanced photovoltaic performance as compared to the devices sensitized by individual dyes. Upon optimization, the device made of 0.3 mM N3 + 0.2 mM RK-1 yielded J(sc) = 18.1 mA cm(2), V-oc = 888 mV, FF = 57.44, and eta = 9.23%. This performance is superior to that of solar cells sensitized with either N3 (6.10%) or RK-1 (5.82%) fabricated under the same conditions. The enhanced efficiency can be attributed to the decrease of the competitive light absorption by I-/I-3(-), dye aggregation, and charge recombination.
机译:证明共同敏化是提高染料敏化太阳能电池效率的有效技术,其中通过混合N3和RK-1染料来实现9.23%的效率。 组装的太阳能电池的特征在于UV-Vis吸收测量,电流 - 电压特性和电化学阻抗光谱。 与通过单独的染料致敏的器件相比,共同敏化的太阳能电池显示出增强的光伏性能。 优化时,由0.3mm N 3 + 0.2mm Rk-1制成的装置产生j(sc)= 18.1 mA cm(2),V-oc = 888mV,ff = 57.44和eta = 9.23%。 这种性能优于在相同条件下制造的N3(6.10%)或RK-1(5.82%)致敏的太阳能电池。 增强效率可归因于I-/ I-3( - ),染料聚集和电荷重组的竞争光吸收的降低。

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  • 来源
    《RSC Advances》 |2016年第10期|共5页
  • 作者单位

    KFUPM RI CoRE RE POB 5050 Dhahran 31261 Saudi Arabia;

    Qatar Univ Coll Engn Gas Proc Ctr POB 2713 Doha Qatar;

    KFUPM RI CoRE RE POB 5050 Dhahran 31261 Saudi Arabia;

    Qatar Fdn Doha Qatar Environm &

    Energy Res Inst Doha Qatar;

    Hamad Bin Khalifa Univ Qatar Environm &

    Energy Res Inst POB 5825 Doha Qatar;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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