Bifunctional Bronsted-Lewis solid acid as a recyclable catalyst for conversion of glucose to 5-hydroxymethylfurfural and its hydrophobicity effect

Wang Xuepeng; Zhang Haijuan; Ma Jingzhong; Ma Zhong-Hua

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Bifunctional Bronsted-Lewis solid acid as a recyclable catalyst for conversion of glucose to 5-hydroxymethylfurfural and its hydrophobicity effect

机译：双官能勃朗斯 - 路易斯固体酸作为可回收催化剂，用于将葡萄糖转化为5-羟甲基糠醛及其疏水性效应

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A novel polydivinylbenzene polymeric material containing water-tolerant SO2NHSO2C4F9 with 2 equivalents of Cr(III) was explored as a catalyst of the one-pot conversion of glucose to 5-hydroxymethylfurfural (HMF) in a biphasic system. Stable 59-57% yields of HMF were achieved throughout 12 cycles over the bifunctional material. Dynamic analysis showed that Cr(III) essentially promoted the isomerization process of glucose to fructose. The material featured integral hydrophobicity, which, with the water-tolerance of SO2NHSO2C4F9, contributed to its excellent recyclability.

机译：含有具有2当量Cr（III）的含有耐水SO2NHSO2C4F9的新型多二硫氨基苯聚合物聚合物材料被探索为双相系统中葡萄糖对5-羟甲基糠醛（HMF）的单罐转化率的催化剂。在整个双官能材料中，在整个12个循环中实现了稳定的59-57％的HMF产率。动态分析表明，Cr（III）基本上促进了葡萄糖的异构化过程。该材料具有整体疏水性，其中具有SO2NSO2C4F9的水分，有助于其优异的可回收性。

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来源
《RSC Advances》 |2016年第49期|共7页
作者
Wang Xuepeng; Zhang Haijuan; Ma Jingzhong; Ma Zhong-Hua;
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Huazhong Agr Univ Coll Sci Dept Chem Wuhan 430070 Peoples R China;

Huazhong Agr Univ Coll Sci Dept Chem Wuhan 430070 Peoples R China;

Huazhong Agr Univ Coll Sci Dept Chem Wuhan 430070 Peoples R China;

Huazhong Agr Univ Coll Sci Dept Chem Wuhan 430070 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Bifunctional Bronsted-Lewis solid acid as a recyclable catalyst for conversion of glucose to 5-hydroxymethylfurfural and its hydrophobicity effect [J] . Wang Xuepeng, Zhang Haijuan, Ma Jingzhong, RSC Advances . 2016,第49期

机译：双官能勃朗斯 - 路易斯固体酸作为可回收催化剂，用于将葡萄糖转化为5-羟甲基糠醛及其疏水性效应
2. Direct conversion of chitosan to 5-hydroxymethylfurfural in water using Bronsted-Lewis acidic ionic liquids as catalysts [J] . Jiang Yi, Zang Hongjun, Han Sheng, RSC Advances . 2016,第105期

机译：使用Bronsted-Lewis酸性离子液作为催化剂将壳聚糖直接转化为水中的5-羟甲基糠醛
3. Cascade conversion of glucose to 5-hydroxymethylfurfural over Bronsted-Lewis bi-acidic SnAl-beta zeolites [J] . An Hyejin, Kweon Sungjoon, Kang Dong-Chang, The Korean journal of chemical engineering . 2021,第6期

机译：血糖转化葡萄糖在Bronsted-Lewis Bi-酸性SnAl-β沸石上的5-羟甲基糠醛转化
4. Selective Catalytic Conversion of Glucose to 5-hydroxymethylfurfural over Zr(H_2PO_4)2 Solid Acid Catalysts [C] . Junpingzhuang, Lu Lin, Chunsheng Pang International Conference on Chemical Engineering and Advanced Materials . 2011

机译：在Zr（H_2PO_4）2固体酸催化剂上的选择性催化转化葡萄糖至5-羟甲基糠醛
5. Selective dehydration of polyols over solid acids and metal-acid bifunctional catalysts: Towards a catalytic toolbox for rational catalyst design. [D] . Nolan, Michael R. 2014

机译：在固体酸和金属酸双功能催化剂上进行多元醇的选择性脱水：成为合理设计催化剂的催化工具箱。
6. Nb2O5-γ-Al2O3 nanofibers as heterogeneous catalysts for efficient conversion of glucose to 5-hydroxymethylfurfural [O] . Huanfeng Jiao, Xiaoliang Zhao, Chunxiao Lv, -1

机译：Nb2O5-γ-Al2O3纳米纤维作为非均相催化剂可有效地将葡萄糖转化为5-羟甲基糠醛
7. Bifunctional Solid Catalysts for the Selective Conversion of Fructose to 5-Hydroxymethylfurfural [O] . Anthony J. Crisci, Mark H. Tucker, James A. Dumesic, 2010

机译：用于将果糖选择性转化为5-羟甲基糠醛的双功能固体催化剂

Bifunctional Bronsted-Lewis solid acid as a recyclable catalyst for conversion of glucose to 5-hydroxymethylfurfural and its hydrophobicity effect

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