• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Efficient conversion of biomass-derived furfuryl alcohol to levulinate esters over commercial alpha-Fe2O3
【24h】

Efficient conversion of biomass-derived furfuryl alcohol to levulinate esters over commercial alpha-Fe2O3

机译：高效转化生物质衍生的糠醇在商业α-Fe2O3上的乙酰丁酯

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

An efficient process for the production of levulinate esters from biomass-derived furfuryl alcohol in liquid alcohol over commercial alpha-Fe2O3 was firstly investigated. Among the catalysts we tested, alpha-Fe2O3, a cheap, commercially available and environmentally benign catalyst, exhibited a remarkable catalytic performance for the transformation and gives levulinate esters in good yield compared to the previous studies. The corresponding esters such as methyl levulinate, ethyl levulinate and butyl levulinate were obtained in high yields under optimized reaction conditions. Several influence factors for the formation of levulinate esters were also discussed. A plausible reaction mechanism for the formation of levulinate ester from furfuryl alcohol was proposed. From the viewpoint of practice and economy, the present study provides a potential application for the efficient synthesis of fine chemicals from biomass-derived compounds over cheap, commercially available and environmentally benign catalysts.
机译：首先研究了在液体醇中，在商业α-Fe 2 O 3上从生物质衍生的呋喃氨磺酰醇中生产从商业alpha-Fe 2 O 3中生产的有效方法。在我们测试的催化剂中，α-Fe2O3，廉价，可商购和环境良性催化剂，其转化表现出显着的催化性能，与先前的研究相比，较好的产率赋予剥离酯。在优化的反应条件下，在高产率下获得相应的酯如甲基乙酰硫酸甲酯，乙酰乙酰乙酰乙烯和丁基丁酸丁酸乙酯。还讨论了用于形成剥离酯的几种影响因素。提出了一种从糠醇中形成氟氨酸酯的合理反应机理。从实践和经济的角度来看，本研究提供了在廉价，可商购和环境良性催化剂的生物质衍生的化合物中有效地合成精细化学物质的潜在应用。

著录项

  • 来源
    《RSC Advances》 |2016年第26期|共5页
  • 作者

    Ren Dezhang; Fu Jun; Li Lu; Liu Yunjie; Jin Fangming; Huo Zhibao;

  • 作者单位

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

    Shanghai Jiao Tong Univ Sch Environm Sci &

    Engn State Key Lab Met Matrix Composites 800 Dongchuan Rd Shanghai 200240 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号