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Synergetic effect of functionalized carbon nanotubes on ZnCr-mixed metal oxides for enhanced solar light-driven photocatalytic performance

机译:官能化碳纳米管对ZnCR混合金属氧化物进行增强太阳光驱动光催化性能的协同作用

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摘要

In this work, ZnCr-mixed metal oxides (MMO) hybridized with functionalized carbon nanotubes (A-CNTs) have been successfully fabricated via vacuum calcination of the layered double hydroxide precursors. The structural and morphological characterization of the samples was investigated by multiple techniques such as XRD, SEM, TEM, XPS, BET, Raman and UV-vis DRS. The results showed that A-CNTs were well incorporated into the MMO nanoparticles to form a nanohybrid structure dependent upon intimate interfacial contact. As compared to pristine MMO, the obtained MMO-CNTs nanohybrids exhibited significantly enhanced photocatalytic performance for bisphenol A (BPA) degradation under simulative solar light irradiation, providing powerful evidence for the superiority of the hybridization with A-CNTs. The key role of A-CNTs played in enhancing the photocatalytic activity of the nanohybrids was probably ascribed to the larger surface area, higher visible light absorption and the more efficient restriction of charge carriers recombination.
机译:在这项工作中,与官能化的碳纳米管(A-CNT)的杂交ZnCr混合金属氧化物(MMO)已经成功地通过层状双氢氧化物前体的真空焙烧制造。样品的结构和形态特征是由多种技术如XRD,SEM,TEM,XPS,BET,拉曼和紫外可见DRS调查。结果表明,A-的CNT以及并入MMO纳米颗粒以形成纳米杂化结构取决于亲密界面接触。相比于原始MMO,所获得的MMO-CNT的纳米复合物表现出增强的显著为双酚A(BPA)的光催化降解性能模拟太阳光照射下,提供与A-碳纳米管杂交的优越性有力的证据。在提高了纳米复合物的光催化活性起到A-碳纳米管的关键作用可能是归属于较大的表面积,较高的可见光吸收和载流子复合的更有效的限制。

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  • 来源
    《RSC Advances》 |2016年第44期|共12页
  • 作者单位

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

    S China Univ Technol Coll Environm &

    Energy Guangzhou 510006 Guangdong Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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