Radical coupling polymerization (RCP) for synthesis of various polymers

Liu Zhe; Wang Qi

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Radical coupling polymerization (RCP) for synthesis of various polymers

机译：用于合成各种聚合物的自由基偶联聚合（RCP）

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A general polymerization method is reported, which involves a direct radical coupling reaction of in situ formed benzyl-type biradicals from dibromide in the presence of a Cu(0)/ligand. The radical coupling polymerization can be employed to synthesize polyarene, polyester, polyether and polysulfone under mild conditions and within a short time.

机译：报道了一般聚合方法，其涉及原位形成的苄基型血管基在Cu（0）/配体存在下的直接自由基偶联反应。可用于在温和条件下和短时间内合成聚乙烯，聚酯，聚醚和聚砜的自由基偶联聚合。

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来源
《RSC Advances》 |2016年第46期|共5页
作者
Liu Zhe; Wang Qi;
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作者单位

Zhejiang Univ Dept Polymer Sci &

Engn Key Lab Macromol Synth &

Functionalizat Minist Educ Hangzhou 310027 Zhejiang Peoples R China;

Zhejiang Univ Dept Polymer Sci &

Engn Key Lab Macromol Synth &

Functionalizat Minist Educ Hangzhou 310027 Zhejiang Peoples R China;

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正文语种 eng
中图分类化学;
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专利

1. Radical coupling polymerization (RCP) for synthesis of various polymers [J] . Liu Zhe, Wang Qi RSC Advances . 2016,第46期

机译：用于合成各种聚合物的自由基偶联聚合（RCP）
2. Synthesis of branched polymers by means of living anionic polymerization, 9 - Radical coupling reaction of 1,1-diphenylethylene-functionalized polymers with potassium naphthalenide and its application to syntheses of in-chain-functionalized polymers [J] . Higashihara T., Hayashi M., Hirao A. Macromolecular chemistry and physics . 2002,第1期

机译：通过活性阴离子聚合，1,1-二苯基乙烯官能化的聚合物与萘化钾的9-自由基偶联反应合成支链聚合物及其在链内官能化聚合物的合成中的应用
3. Photoactivation of Organotellurium Compounds in Precision Polymer Synthesis: Controlled Radical Polymerization and Radical Coupling Reactions [J] . Yamago Shigeru Bulletin of the Chemical Society of Japan . 2020,第2期

机译：精密聚合物合成中有机纤维素化合物的光痉挛：控制自由基聚合和自由基偶联反应
4. Radical Coupling of Polymers Formed by Cobalt-Mediated Radical Polymerization [C] . Antoine Debuigne, Marie Hurtgen, Christine Jerome, American Chemical Society symposium on controlled/living radical polymerization . 2012

机译：通过钴介导的自由基聚合反应形成的聚合物的自由基偶联
5. "Living"/controlled radical polymerization: From emulsion atom transfer radical polymerization to the synthesis of new nitroxides for stable free radical polymerization. [D] . Chan-Seng, Delphine. 2007

机译：“活性” /受控自由基聚合：从乳液原子转移自由基聚合到合成新的氮氧化物以稳定自由基聚合。
6. Synthesis of Monodisperse Silica Particles Grafted with Concentrated Ionic Liquid-Type Polymer Brushes by Surface-Initiated Atom Transfer Radical Polymerization for Use as a Solid State Polymer Electrolyte [O] . Takashi Morinaga, Saika Honma, Takeo Ishizuka, 2010

机译：通过表面引发的原子转移自由基聚合合成固态离子液体型聚合物刷接枝的单分散二氧化硅颗粒，用作固态聚合物电解质
7. Photoactivation of Organotellurium Compounds in Precision Polymer Synthesis: Controlled Radical Polymerization and Radical Coupling Reactions [O] . Shigeru Yamago 2020

机译：精密聚合物合成中有机纤维素化合物的光痉挛：控制自由基聚合和自由基偶联反应

Radical coupling polymerization (RCP) for synthesis of various polymers

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