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Synthesis of high quality CuO nanoflakes and CuO-Au nanohybrids for superior visible light photocatalytic behavior

机译:高品质CuO纳米薄片的合成和CuO-Au纳米冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬冬美

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摘要

Well-defined CuO nanoflakes and CuO-Au nanohybrids are successfully obtained by a facile but effective wet chemistry synthesis method. Compared with CuO nanoflakes, the formation of high-quality CuO-Au nanohybrids can improve the visible light absorption efficiency, charge generation and separation efficiency through surface plasmon resonance (SPR), thus yielding remarkably enhanced photoelectrochemical and photocatalytic activities. CuO-Au nanohybrids with an optimized Au nanoparticle loading concentration (10 wt%) and particle size (similar to 15 nm) present the highest photocurrent density (46 mA cm(-2)) and degradation rate constant (k = 0.64 h(-1)), which are almost similar to 4 times higher than those of the CuO nanoflakes. The high photocatalytic properties and robust synthesis of CuO-Au nanohybrids can expand new material systems for the visible light utilization of solar energy and effective treatment of organic pollutants.
机译:通过容易但有效的湿化学合成方法成功地获得明确定义的CuO纳米薄片和CuO-Au纳米胺。 与CuO纳米薄膜相比,通过表面等离子体共振(SPR)形成高质量的Cuo-Au纳米露出的形成可以提高可见光吸收效率,电荷产生和分离效率,从而产生显着增强的光电化和光催化活性。 具有优化的Au纳米颗粒加载浓度(10wt%)和粒度(类似于15nm)的CuO-Au纳米冬次含有最高的光电流密度(46mA cm(-2))和降解速率常数(k = 0.64h( - 1)),几乎与CuO纳米薄片高4倍。 CuO-Au纳米油状的高光催化性能和鲁棒合成可以扩大用于可见光利用太阳能和有效污染物的有效处理的新材料系统。

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  • 来源
    《RSC Advances》 |2016年第85期|共7页
  • 作者单位

    Xi An Jiao Tong Univ Frontier Inst Sci &

    Technol Jointly Coll Sci State Key Lab Mech Behav Mat Xian 710049 Shaanxi Peoples R China;

    Xi An Jiao Tong Univ Sch Elect &

    Informat Engn Int Ctr Dielect Res Minist Educ Key Lab Elect Mat Res Lab Xian 710049 Shaanxi Peoples R China;

    Xi An Jiao Tong Univ Sch Elect &

    Informat Engn Int Ctr Dielect Res Minist Educ Key Lab Elect Mat Res Lab Xian 710049 Shaanxi Peoples R China;

    Xi An Jiao Tong Univ Frontier Inst Sci &

    Technol Jointly Coll Sci State Key Lab Mech Behav Mat Xian 710049 Shaanxi Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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