Design and synthesis of new ruthenium complex for dye-sensitized solar cells

Murali M. G.; Wang Xingzhu; Wang Qing; Valiyaveettil Suresh

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Design and synthesis of new ruthenium complex for dye-sensitized solar cells

机译：染料敏化太阳能电池新型钌配合物的设计与合成

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A series of ruthenium complexes (MC-1-MC-3), incorporated with carbazole, fluorene and phenothiazine units with dipyrido[3,2-a: 2',3'-c] phenazine are synthesized, characterized and their optical, electrochemical and photovoltaic properties are investigated. The observed differences in light-harvesting ability of the sensitizers are associated with the electron donor strength of the ancillary ligand used for preparing complexes. The dye-sensitized solar cell fabricated from complex MC-1 exhibited a power conversion efficiency of 6.18%. It is demonstrated that new molecular design and increase in molar absorption coefficient of the sensitizer improved the device performance.

机译：一系列钌配合物（MC-1-MC-3），与咔唑，芴和吩噻嗪单元掺入具有双吡啶[3,2-A：2'，3'-C]苯脲的苯脲，其特征及其光学，电化学并研究了光伏性能。观察到敏感剂的光收获能力的差异与用于制备配合物的辅助配体的电子供体强度有关。从复合MC-1制造的染料敏化太阳能电池表现出6.18％的功率转换效率。结果表明，敏感剂的新分子设计和摩尔吸收系数的增加改善了装置性能。

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来源
《RSC Advances》 |2016年第63期|共8页
作者
Murali M. G.; Wang Xingzhu; Wang Qing; Valiyaveettil Suresh;
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Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

Natl Univ Singapore NanoCore NUSNNI 5A Engn Dr 1 Singapore 117411 Singapore;

Natl Univ Singapore NanoCore NUSNNI 5A Engn Dr 1 Singapore 117411 Singapore;

Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

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正文语种 eng
中图分类化学;
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1. The design and synthesis of thiophene-based ruthenium(II) complexes as promising sensitizers for dye-sensitized solar cells [J] . Medvedko A. V., Ivanov V. K., Kiskin M. A., Dyes and Pigments . 2017,第期

机译：基于噻吩基钌（II）配合物的设计与合成作为染料敏化太阳能电池的有前途敏化剂
2. Improved performance with molecular design of Ruthenium(II) complexes bearing diamine-based bidentate ligands as sensitizer for dye-sensitized solar cells (DSSC) [J] . Journal of Molecular Structure . 2020,第期

机译：改进了钌（II）复合物的分子设计的性能，其轴承二胺的双齿配体作为染料敏化太阳能电池的敏化剂（DSSC）
3. Design and development of cyclometalated ruthenium complexes containing thiophenyl-pyridine ligand for dye-sensitized solar cells [J] . Chung-Yen Li, Chaochin Su, Hsiou-Hsuan Wang Dyes and Pigments . 2014,第Null期

机译：用于染料敏化太阳能电池的含硫代苯基吡啶配体的环金属化钌配合物的设计和开发
4. Two Ruthenium Complexes with Phenanthroline Ligand for Dye-Sensitized Solar Cells [C] . Yuranan Thathong, Kittiya Wongkhan, Rukkiat Jitchati International Conference on Engineering Materials . 2013

机译：两种钌配合物用菲咯啉配体用于染料敏化太阳能电池
5. I. Ground-state association between phenothiazine and tris(diimine)ruthenium(II) complexes: Its role in highly efficient photoinduced charge separation. II. Ligand modifications of cobalt complexes to increase efficiency of electron-transfer mediators in dye-sensitized solar cells [D] . Weber, John 2012

机译：一，吩噻嗪与三（二亚胺）钌（II）配合物之间的基态缔合：在高效光诱导电荷分离中的作用。二。钴配合物的配体修饰，以提高染料敏化太阳能电池中电子转移介体的效率
6. Characterization of Photovoltaic Performance of the Dye-Sensitized Solar Cell with a Novel Ruthenium Complex Having a Bisdemethoxycurcumin as a Ligand [O] . Hironobu Ozawa, Hiroki Kawaguchi, Yu Okuyama, 2012

机译：用双去甲氧基姜黄素作为配体的新型钌配合物表征染料敏化太阳能电池的光伏性能
7. Development Of Ruthenium Complex Based Sensitizers, Organic Based Sensitizers, And Co-Sensitization System For Dye-Sensitized Solar Cells [O] . Chan K.F. 2020

机译：基于钌的敏化剂，有机敏化剂和染料敏化太阳能电池共敏化系统的研制

Design and synthesis of new ruthenium complex for dye-sensitized solar cells

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