• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>RSC Advances >Smart stimuli-responsive fluorescent vesicular sensor based on inclusion complexation of cyclodextrins with Tyloxapol
【24h】

Smart stimuli-responsive fluorescent vesicular sensor based on inclusion complexation of cyclodextrins with Tyloxapol

机译：智能刺激荧光囊泡传感器，基于泰诺普酚的环糊精的包涵体络合

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Novel fluorescent vesicles based on inclusion complexes of beta-cyclodextrins (beta-CD) with Tyloxapol were constructed. For comparison, alpha-cyclodextrins (alpha-CD) were also selected to form inclusion complexes with Tyloxapol. The vesicles formed by beta-CD/Tyloxapol were characterized thoroughly using various techniques including phase behavior observation, transmission electron microscopy (TEM), freeze fracture transmission electron microscopy (FF-TEM), field emission scanning electron microscopy (FESEM), atomic force microscopy (AFM), 2D H-1-H-1 ROESY NMR, fluorescence spectra, Fourier transform infrared (FT-IR) spectroscopy, and X-ray diffraction (XRD). The results of TEM, SEM, FF-TEM, AFM indicated the formation of vesicles of beta-CD/Tyloxapol; they presented aggregation-induced emission enhancement properties because the alkyl chain of Tyloxapol molecules enters the cavity of beta-CD and forms inclusion complexes, while alpha-CD/Tyloxapol showed aggregation-induced quenching fluorescence emission properties owing to the interaction between PEO chain of Tyloxapol molecules and alpha-CD. Moreover, the vesicles of beta-CD/Tyloxapol were responsive to external stimuli and their fluorescent intensities were changed by various environmental conditions such as urea, phenylalanine, alpha-amylase and NaOH. These properties made our vesicle a promising candidate as novel, smart, stimuli-responsive, fluorescent vesicular sensors.
机译：构建了基于β-环糊精（β-CD）的包合物的新型荧光囊泡与甲氧普氏醇。为了比较，还选择α-环糊精（α-CD）以形成含钛藻的包合物。通过β-CD / Tyloxapol形成的囊泡，用各种技术进行彻底使用，所述各种技术包括相行为观察，透射电子显微镜（TEM），冷冻骨折透射电子显微镜（FF-TEM），场发射扫描电子显微镜（FESEM），原子力显微镜检查（AFM），2D H-1-H-1 Roesy NMR，荧光光谱，傅里叶变换红外（FT-IR）光谱和X射线衍射（XRD）。 TEM，SEM，FF-TEM，AFM的结果表明了β-CD / Tyloxapol囊泡的形成;它们呈现聚集诱导的发射增强性能，因为甲氧肟氏醇分子的烷基链进入β-CD的腔体并形成包合物复合物，而α-Cd / Tyloxapol由于Tyloxapol的PEO链之间的相互作用而显示聚集诱导的猝灭荧光发射性能分子和α-CD。此外，β-Cd / Tyloxapol的囊泡对外部刺激响应，并且它们的荧光强度由尿素，苯丙氨酸，α-淀粉酶和NaOH等各种环境条件改变。这些属性使我们的囊泡成为新颖，智能，刺激荧光囊泡传感器的有前途的候选者。

著录项

  • 来源
    《RSC Advances》 |2016年第14期|共8页
  • 作者

    Shen Jinglin; Pang Jinyu; Xu Guiying; Xin Xia; Yang Yingjie; Luan Xiaoyu; Yuan Shiling;

  • 作者单位

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

    Shanxi Transportat Res Inst Taiyuan 030006 Peoples R China;

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

    Shandong Univ Key Lab Colloid &

    Interface Chem Minist Educ Shanda Nanlu 27 Jinan 250100 Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号