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Enhanced ethanol gas sensing performance of zinc-tin-vanadium oxide nanocomposites at room temperature

机译:增强锌 - 锡钒氧化物纳米复合材料的乙醇气体感测性能在室温下

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摘要

A zinc-tin-vanadium oxide (ZTV) nanocomposite is synthesised via a hydrothermal route followed by calcination, characterised by various state-of-the-art techniques and tested for ethanol sensing behaviour (0-300 ppm) at room temperature. The synergistic effect made ZTV a unique ethanol sensor (98.96%) with a fast adsorption and desorption rate of 32 s and 6 s, respectively. The morphological contribution from the zinc-tin oxide nanocomposite (ZT) and zinc-vanadium oxide nanocomposite (ZV) in the ZTV system provides a larger surface area which in turn promotes a higher number of surface active sites for the adsorption of ethanol molecules on the surface. The catalytic activity along with different reductive-oxidative states had a larger impact on the enhanced ethanol sensing ability of the ZTV system even at room temperature. In this present work, the novel material, ZTV which exhibits excellent ethanol sensing characteristics at room temperature is investigated and the mechanism behind the sensing behaviour of ZTV is elucidated based on its structure and morphology.
机译:通过水热路径合成锌 - 氧化铟氧化物(ZTV)纳米复合材料,然后通过煅烧合成,其特征在于各种最先进的技术,并在室温下测试乙醇感测行为(0-300ppm)。协同效应使ZTV独特的乙醇传感器(98.96%)分别具有32秒和6秒的快速吸附和解吸速率。 ZTV系统中锌氧化锌纳米复合材料(ZT)和锌 - 钒氧化物纳米复合材料(ZV)的形态学贡献提供了较大的表面积,其又促进了乙醇分子吸附的较高数量的表面活性位点表面。催化活性以及不同的还原氧化状态对ZTV系统的增强乙醇感测能力甚至在室温下产生较大的影响。在本工作中,研究了在室温下表现出优异的乙醇感测特性的新型材料ZTV,并且基于其结构和形态,阐明了ZTV的感测行为背后的机制。

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  • 来源
    《RSC Advances》 |2016年第112期|共13页
  • 作者单位

    Sri Ramakrishna Engn Coll Dept Phys Coimbatore 641022 Tamil Nadu India;

    Sri Ramakrishna Engn Coll Dept Phys Coimbatore 641022 Tamil Nadu India;

    Sri Ramakrishna Engn Coll Dept Chem Coimbatore 641022 Tamil Nadu India;

    Sri Ramakrishna Engn Coll Dept Chem Coimbatore 641022 Tamil Nadu India;

    Periyar Univ Dept Phys Salem 636011 India;

    Manonmaniam Sundaranar Univ Dept Phys Abhishekapatti 627012 Tirunelveli India;

    Indira Gandhi Ctr Atom Res Mat Sci Grp Surface &

    Nanosci Div Kalpakkam 603102 Tamil Nadu India;

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  • 正文语种 eng
  • 中图分类 化学;
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