A Ru(III) - catalyzed alpha-cross-coupling aldol type addition reaction of activated olefins with isatins

Kumar A. Sanjeeva; Ramesh Palakuri; Kumar G. Santosh; Swetha A.; Nanubolu Jagadeesh Babu; Meshram H. M.

首页> 外文期刊>RSC Advances >A Ru(III) - catalyzed alpha-cross-coupling aldol type addition reaction of activated olefins with isatins

【24h】

A Ru(III) - catalyzed alpha-cross-coupling aldol type addition reaction of activated olefins with isatins

机译：Ru（III） - 用异脂蛋白催化活性烯烃的α-交联醛醇类别加成反应

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A alpha-cross-coupling aldol type addition reaction activated olefins with isatins has been described in the presence of ruthenium(III) chloride and tributyltin hydride (TBTH) at room temperature. This method is found to work consistently for the delivering of ene-carbonyl coupled products in good to excellent yields with moderate to acceptable selectivity. The substrate scope of the present method was briefly discussed.

机译：在室温下在钌（III）氯化钌和三丁基锡（TBTH）存在下，已经在室温下描述了具有甲磺酸酯的α-交联醛醇类别加成反应活化烯烃。发现该方法一致地用于赋予烯-羰基偶联产物的优异产率，其具有中等至可接受的选择性。简要讨论了本方法的衬底范围。

著录项

来源
《RSC Advances》 |2016年第3期|共5页
作者
Kumar A. Sanjeeva; Ramesh Palakuri; Kumar G. Santosh; Swetha A.; Nanubolu Jagadeesh Babu; Meshram H. M.;
展开▼
作者单位

Indian Inst Chem Technol Med Chem &

Pharmacol Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol Med Chem &

Pharmacol Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol Med Chem &

Pharmacol Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol Med Chem &

Pharmacol Div Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol Lab Xray Crystallog Hyderabad 500007 Andhra Pradesh India;

Indian Inst Chem Technol Med Chem &

Pharmacol Div Hyderabad 500007 Andhra Pradesh India;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. A Ru(III) - catalyzed alpha-cross-coupling aldol type addition reaction of activated olefins with isatins [J] . Kumar A. Sanjeeva, Ramesh Palakuri, Kumar G. Santosh, RSC Advances . 2016,第3期

机译：Ru（III） - 用异脂蛋白催化活性烯烃的α-交联醛醇类别加成反应
2. Ruthenium-Catalyzed Tandem Olefin Migration/Aldol and Mannich-Type Reactions in Water and Protic Solvents [J] . Mingwen Wang, Xiao-Fan Yang, Chao-Jun Li European journal of organic chemistry . 2003,第6期

机译：在水和质子传递溶剂中钌催化的串联烯烃迁移/醛醇和曼尼希型反应
3. Addition reaction of 2-phenylbenzoic acid onto unactivated olefins catalyzed by Ru(II)-xantphos catalysis [J] . Yohei Oe, Tetsuo Ohta, Yoshihiko Ito Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第21期

机译：Ru（II）-xantphos催化的2-苯基苯甲酸与未活化烯烃的加成反应
4. Addition Reactions of Heteroatom Nucleophiles onto Olefins with New Xantphos-Ru Complexes [C] . Yohei Oe, Hiroto Takenaka, Tetsuo Ohta Symposium on Organometallic Chemistry . 2008

机译：用新的Xantphos-Ru复合物加入杂原子官亲核试剂对烯烃的反应
5. Methodology and Mechanistic Studies for Indium(III)- and Scandium(III)-Pybox Catalyzed Additions of Pyrroles and pi-Nucleophiles to Isatins for Enantioselective Synthesis of Oxindoles. [D] . Gutierrez, Elisa Graciela. 2014

机译：铟（III）-和Scan（III）-Pybox催化将吡咯和π-亲核试剂加成到Isatins上的方法和机理研究，用于对映选择性合成羟吲哚。
6. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid [O] . Tyler A. Davis, Chuanqi Wang, Tomislav Rovis -1

机译：铑（III）催化的C H活化：羧酸指导的氧化分子内Heck型反应。
7. Palladium-Catalyzed Decarboxylative Aza-Michael Addition-Allylation Reactions between Allyl Carbamates and Activated Olefins. Generation of Quaternary Carbon Adjacent to Secondary Amine Carbon Center [O] . -1

机译：钯催化的脱羧AZA-MICHAEL添加 - 烯丙基氨基甲酸酯和活性烯烃之间的烯丙基化反应。仲胺碳中心相邻的季碳产生

A Ru(III) - catalyzed alpha-cross-coupling aldol type addition reaction of activated olefins with isatins

摘要

著录项

相似文献

相关主题

期刊订阅