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Anion coordinated capsules and pseudocapsules of tripodal amide, urea and thiourea scaffolds

机译:阴离子协调胶囊和三级酰胺,尿素和硫脲脚手架的假胶囊

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摘要

This review aims to deliver a detailed and comparative account of the reported examples of anion (halide and oxyanions) coordinated capsules and pseudocapsules of tripodal receptors that employ hydrogen bonds and/or electrostatic hydrogen bonds offered by specific binding sites from amide, urea and thiourea functionalities. The review discusses both the structural aspects of anion binding and solution-state anion binding affinities of N-bridged and aryl-bridged tripodal receptors. Discussions relating to selective anion recognition and separation, carbondioxide uptake, and transmembrane anion transport, as demonstrated by some of these tripodal receptors have also been included in this review.
机译:本综述旨在提供报告的阴离子(卤化物和氧气)的实施例的详细和比较叙述,所述三码胶囊和伪致胶囊的初级受体,其采用来自酰胺,尿素和硫脲官能团的特异性结合位点提供的氢键和/或静电氢键 。 审查讨论了N-桥接和芳基 - 桥接三架构受体的阴离子结合和溶液状态阴离子结合亲和力的结构方面。 与这些三级透镜受体中所证明的那样讨论有关选择性阴离子识别和分离,碳二氧化锑摄取和跨膜阴离子运输的讨论也被列入了这篇综述。

著录项

  • 来源
    《RSC Advances》 |2016年第32期|共22页
  • 作者单位

    Indian Inst Technol Guwahati Dept Chem Gauhati 781039 Assam India;

    Indian Inst Technol Guwahati Dept Chem Gauhati 781039 Assam India;

    Indian Inst Technol Guwahati Dept Chem Gauhati 781039 Assam India;

    Indian Inst Technol Guwahati Dept Chem Gauhati 781039 Assam India;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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