Palladium-catalyzed reductive Heck-type vinylative dearomatization of unfunctionalized halonaphthalene derivatives

Dou Yingchao; Yang Liting; Zhang Lu; Zhang Panke; Li Heng; Yang Guanyu

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Palladium-catalyzed reductive Heck-type vinylative dearomatization of unfunctionalized halonaphthalene derivatives

机译：钯催化的减少的未官能化卤代酚衍生物的乙烯酸酯化

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摘要

A novel strategy for the dearomatization of inactive 1-halonaph-thalenes via palladium-catalyzed reductive Heck-type vinylative reaction was successfully developed. Both homo- and hetero-cyclic naphthalene derivatives were tolerated, and the desired products were obtained in modest to good yields.

机译：通过钯催化的还原性Heck型乙烯化反应成功开发了一种新的一种用于无活性的1-卤代 - 替替萘醇类的新策略。耐受同源和杂环萘衍生物，并且在适度以良好的产率下获得所需产物。

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《RSC Advances》 |2016年第102期|共4页
作者
Dou Yingchao; Yang Liting; Zhang Lu; Zhang Panke; Li Heng; Yang Guanyu;
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作者单位

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

Zhengzhou Univ Coll Chem &

Mol Engn Zhengzhou 450001 Henan Peoples R China;

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正文语种 eng
中图分类化学;
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1. Palladium-catalyzed reductive Heck-type vinylative dearomatization of unfunctionalized halonaphthalene derivatives [J] . Dou Yingchao, Yang Liting, Zhang Lu, RSC Advances . 2016,第102期

机译：钯催化的减少的未官能化卤代酚衍生物的乙烯酸酯化
2. Palladium-Catalyzed Intermolecular Heck-Type Dearomative [4+2] Annulation of 2H-Isoindole Derivatives with Internal Alkynes [J] . Yao Tengfei, Zhang Fang, Zhang Junliang, Organic letters . 2020,第13期

机译：钯 - 催化的分子间Heck型Deacomative [4 + 2]含有内部炔烃的2H-异吲哚衍生物
3. Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes [J] . Gianluigi Broggini, Egle M. Beccalli, Andrea Fasana, Beilstein journal of organic chemistry. . 2012,第1期

机译：钯催化未官能化吲哚衍生物与烯烃和芳烃的双CH或NH官能化
4. Kinetic Resolution of Chiral Vinyl Ether via Palladium-Catalyzed Alcoholysis [C] . Takeshi Sakuma, Hisashi Ita, Eiji Yamamoto Symposium on Organometallic Chemistry . 2008

机译：通过钯催化醇解的手性乙烯基醚的动力分辨率
5. Part I: The Study of 2-Aryl-1,3-Dithiane Derivatives As Pronucleophiles in Palladium-Catalyzed Allylic Alkylation and Propellylation Part II: Ligand-Free Palladium-Catalyzed Allylic Amintion of Hydrazone Derivatives Part III: Synthesis of Criegee Intermed [D] . Trongsiriwat, Nisalak. 2019

机译：第一部分：将2-芳基-1,3-二硫醚衍生物的研究作为钯催化的烯丙基烷基化和预选型第II部分：腙衍生物的配体钯催化烯丙基胺部分III：Criaegee中间的合成
6. Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes [O] . Gianluigi Broggini, Egle M Beccalli, Andrea Fasana, 2012

机译：钯催化未官能化吲哚衍生物与烯烃和芳烃的双CH或NH官能化
7. Palladium-catalyzed dual C–H or N–H functionalization of unfunctionalized indole derivatives with alkenes and arenes [O] . Gianluigi Broggini, Egle M. Beccalli, Andrea Fasana, 2012

机译：钯催化双C＆H; N或N＆＃8211; H官能化非官能化吲哚衍生物与烯烃和芳烃

Palladium-catalyzed reductive Heck-type vinylative dearomatization of unfunctionalized halonaphthalene derivatives

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