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In situ polymerization approach to functionalized MoS2/polyethylene nanocomposites with enhanced thermal stability and mechanical properties

机译:以增强的热稳定性和机械性能,原位聚合方法以官能化MOS2 /聚乙烯纳米复合材料

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摘要

Bulk MoS2 was chemically exfoliated and functionalized with a long alkyl amine (octadecylamine, ODA) and subsequently used as a component in the preparation of an (ODA)-MoS2/MgCl2/TiCl4 catalyst through a coagglomeration method. After in situ ethylene polymerization, flake shape polyethylene (PE)/ODA-MoS2 nanocomposites were obtained, and the ODA-MoS2 fillers were well dispersed in the PE matrix with strong interfacial adhesion. Additionally, the thermal stability and mechanical properties of PE were significantly enhanced by incorporation of the ODA-MoS2 fillers. Therefore, the in situ polymerization approach proposed here will open a new and exciting avenue for the development of transition metal dichalcogenide reinforced polyolefin nanocomposites.
机译:将块状MOS2化学剥离和用长烷基胺(十八烷基胺,ODA)进行化学剥离和官能化,随后用作通过凝聚方法制备(ODA)-MOS2 / MgCl 2 / TiCl4催化剂的组分。 在原位乙烯聚合之后,得到薄片形状聚乙烯(PE)/ ODA-MOS2纳米复合材料,并且在具有强界面粘附的PE基质中,ODA-MOS2填料很好地分散。 另外,通过掺入ODA-MOS2填料,PE的热稳定性和机械性能明显增强。 因此,本文提出的原位聚合方法将开启过渡金属二甲基酯增强聚烯烃纳米复合材料的开发新的和激动的途径。

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  • 来源
    《RSC Advances》 |2016年第113期|共6页
  • 作者单位

    Jilin Agr Univ Coll Food Sci &

    Engn Natl Engn Lab Wheat &

    Corn Deep Proc Changchun Peoples R China;

    Kyungpook Natl Univ Dept Polymer Sci &

    Engn Daegu South Korea;

    Chinese Acad Sci Changchun Inst Appl Chem Key Lab Synthet Rubber Beijing 100864 Peoples R China;

    Kyungpook Natl Univ Dept Polymer Sci &

    Engn Daegu South Korea;

    Kyungpook Natl Univ Dept Polymer Sci &

    Engn Daegu South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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