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A review on Mn4+ activators in solids for warm white light-emitting diodes

机译:暖白发光二极管固体Mn4 +活化剂的综述

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摘要

Currently, the major commercial white light-emitting diodes consist of a blue-emitting chip and Y3Al5O12:Ce3+ yellow phosphor. However, the shortage of a red emitting component in the constructed device makes it difficult to realize warm white light with a high color-rendering index and low correlated color temperature. In this mini-review article, we provide an overview of recent progresses in developing Mn4+ doped red phosphors for promising applications in warm white light-emitting diodes. Firstly, the spectroscopic properties of Mn4+ in solids, including electronic and vibronic energy-level structures, crystal-field parameters as well as thermal stability, were briefly discussed. And then the related physical and chemical synthesis strategies were introduced in detail. Afterwards, Mn4+ doped phosphors, such as oxides, fluorides as well as glass ceramic composites, and their impact on improving the photoelectric performance of white light-emitting diodes were summarized. Finally, several challenges and perspectives for exploring novel and high-performance Mn4+ doped red phosphors will be presented.
机译:目前,主要的商业白光二极管包括蓝色发光芯片和Y3Al5O12:CE3 +黄色磷光体。然而,构造装置中的红色发射部件的短缺使得难以实现具有高色彩渲染指数和低相关色温的暖白光。在此迷你审查文章中,我们概述了近期开发MN4 +掺杂红磷光体的进展,以便在暖白发光二极管中有前途的应用。首先,简要讨论了固体中Mn4 +的光谱性能,包括电子和振动能量水平结构,晶体场参数以及热稳定性。然后详细介绍了相关的物理和化学合成策略。然后,总结了MN4 +掺杂磷光体,例如氧化物,氟化物以及玻璃陶瓷复合材料,以及它们对改善白光发光二极管的光电性能的影响。最后,将介绍探索新型和高性能MN4 +掺杂红磷光体的几个挑战和观点。

著录项

  • 来源
    《RSC Advances》 |2016年第89期|共12页
  • 作者单位

    Hangzhou Dianzi Univ Coll Mat &

    Environm Engn Hangzhou 310018 Zhejiang Peoples R China;

    Hangzhou Dianzi Univ Coll Mat &

    Environm Engn Hangzhou 310018 Zhejiang Peoples R China;

    Hangzhou Dianzi Univ Coll Mat &

    Environm Engn Hangzhou 310018 Zhejiang Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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