Ionic liquids derived from organosuperbases: en route to superionic liquids

Nowicki Janusz; Muszynski Marcin; Mikkola Jyri-Pekka

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Ionic liquids derived from organosuperbases: en route to superionic liquids

机译：来自有机核蛋白酶的离子液体：在上层液体途中

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Interest in ionic liquids with guanidine, amidine and other superbasic cations has grown markedly in recent years. The syntheses, characterization and properties of protic and quaternary alkylated salts based on cyclic or acyclic guanidine and amidine derivatives have been described in detail. By modifying the anion or the cation, a wide range of properties of superbasic ionic liquids can be tuned, including viscosity, melting point, density, conductivity, solubility, liquid range, and thermal and hydrolytic stability. They are promising solvents for electrochemical, photovoltaic and various synthetic applications, in particular as specific catalysts. Owing to their specific properties, superbasic ionic liquids can be used in applications of great industrial importance such as CO2, SO2 or COS chemisorption.

机译：近年来，对具有胍，脒和其他超快速阳离子的离子液体的兴趣显着增加。已经详细描述了基于环状或无循环胍和脒衍生物的质子和季烷基化盐的合成，表征和性质。通过改变阴离子或阳离子，可以调节各种超基离子液体的性质，包括粘度，熔点，密度，导电性，溶解度，液体范围和热和水解稳定性。它们是用于电化学，光伏和各种合成应用的溶剂，特别是作为特定催化剂。由于它们的特异性，优越的离子液体可用于诸如CO2，SO2或COS化学等巨大的工业重要性的应用中。

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来源
《RSC Advances》 |2016年第11期|共15页
作者
Nowicki Janusz; Muszynski Marcin; Mikkola Jyri-Pekka;
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作者单位

Blachownia Heavy Organ Synth Inst Energetykow 9 PL-47225 Kedzierzyn Kozle Poland;

Blachownia Heavy Organ Synth Inst Energetykow 9 PL-47225 Kedzierzyn Kozle Poland;

Umea Univ Chem Biol Ctr Dept Chem Tech Chem SE-90871 Umea Sweden;

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正文语种 eng
中图分类化学;
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1. Ionic liquids derived from organosuperbases: en route to superionic liquids [J] . Nowicki Janusz, Muszynski Marcin, Mikkola Jyri-Pekka RSC Advances . 2016,第11期

机译：来自有机核蛋白酶的离子液体：在上层液体途中
2. Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly [J] . Zhang Biao, Yan Xibo, Alcouffe Pierre, ACS Macro Letters . 2015,第9期

机译：咪唑型离子液体单体的水RAFT聚合：通过RAFT聚合诱导的自组装向基于聚（离子液体）的纳米粒子的途中
3. Synthesis and Characterization of New Pyrrolidinium Based Protic Ionic Liquids.Good and Superionic Liquids [J] . Meriem Anouti, Magaly Caillon-Caravanier, Yosra Dridi The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2008,第42期

机译：新型吡咯烷鎓质子离子液体，优良和超离子液体的合成与表征
4. Ionic Liquids, Superionic glasses, Quasi-Ionic Liquids, Quasi-Liquid Ionics, all with High Conductivities but some with Little Fluidity. Where does the Paradigm End? [C] . C. Austen Angell Molten salts and ionic liquids 19 . 2014

机译：离子液体，超离子玻璃，准离子液体，准液体离子液体，均具有高电导率，但有些具有低流动性。范例在哪里结束？
5. Polar ionic media and stabilized charged species in organic synthesis: Ionic liquids derived from a biorenewable source, D-fructose, as a possible alternative to conventional organic reaction solvents. [D] . Okello, Maurice O. 2004

机译：有机合成中的极性离子介质和稳定的带电物种：来源于生物可再生来源D-果糖的离子液体，可以作为常规有机反应溶剂的替代方法。
6. Self‐Assembly of Aminocyclopropenium Salts: En Route to Deltic Ionic Liquid Crystals [O] . Dr. Juri Litterscheidt, Prof. Dr. Jeffrey S. Bandar, Max Ebert, -1

机译：氨基环丙烯盐的自组装：通往Deltic离子液晶的途径
7. Technoeconomic Assessment of a Biomass Pretreatment + Ionic Liquid Recovery Process with Aprotic and Choline Derived Ionic Liquids [O] . -1

机译：用非质子和胆碱衍生离子液体的生物质预处理+离子液体回收过程的技术经济评估

Ionic liquids derived from organosuperbases: en route to superionic liquids

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