Benzoic hydroxamate-based iron complexes as model compounds for humic substances: synthesis, characterization and algal growth experiments

Orlowska Ewelina; Roller Alexander; Wiesinger Hubert; Pignitter Marc; Jirsa Franz; Krachler Regina; Kandioller Wolfgang; Keppler Bernhard K.

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Benzoic hydroxamate-based iron complexes as model compounds for humic substances: synthesis, characterization and algal growth experiments

机译：基于苯甲酸苯甲酸的铁络合物作为腐殖质物质的模型化合物：合成，表征和藻类生长实验

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A series of monomeric and dimeric Fe-III complexes bearing benzoic hydroxamates as O,O-chelates has been prepared and characterized by elemental analysis, IR spectroscopy, UV-Vis spectroscopy, electrospray ionization mass spectrometry (ESI-MS), cyclic voltammetry, EPR spectroscopy and for some examples by X-ray diffraction analysis. The stability of the synthesized complexes in pure water and seawater was monitored over 24 h by means of UV-Vis spectrometry. The ability to release iron from the synthesized model complexes has been investigated with algae growth experiments.

机译：一系列单体和二聚体Fe-III复合物轴承苯甲酸苯甲酸盐，通过元素分析，IR光谱，UV-Vis光谱，电喷雾电离质谱（ESI-MS），循环伏安法，EPR 光谱学和X射线衍射分析的一些实例。通过UV-Vis光谱测定，在24小时内监测纯水和海水中合成复合物的稳定性。通过藻类生长实验研究了从合成式复合物中释放铁的能力。

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《RSC Advances》 |2016年第46期|共12页
作者
Orlowska Ewelina; Roller Alexander; Wiesinger Hubert; Pignitter Marc; Jirsa Franz; Krachler Regina; Kandioller Wolfgang; Keppler Bernhard K.;
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Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Dept Nutr &

Physiol Chem Althanstr 14-UZA 2 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

Univ Vienna Fac Chem Inst Inorgan Chem Waehringer Str 42 A-1090 Vienna Austria;

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正文语种 eng
中图分类化学;
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1. Benzoic hydroxamate-based iron complexes as model compounds for humic substances: synthesis, characterization and algal growth experiments [J] . Orlowska Ewelina, Roller Alexander, Wiesinger Hubert, RSC Advances . 2016,第46期

机译：基于苯甲酸苯甲酸的铁络合物作为腐殖质物质的模型化合物：合成，表征和藻类生长实验
2. Synthetic iron complexes as models for natural iron-humic compounds: Synthesis, characterization and algal growth experiments [J] . Ewelina Orlowska, Alexander Roller, Marc Pignitter, The Science of the Total Environment . 2017,第JANa15期

机译：合成铁络合物作为天然铁腐殖质化合物的模型：合成，表征和藻类生长实验
3. beta-O-4 type dilignol compounds and their iron complexes for modeling of iron binding to humic acids: synthesis, characterization, electrochemical studies and algal growth experiments [J] . Orlowska Ewelina, Enyedy Eva A., Pignitter Dmarc, New Journal of Chemistry . 2017,第20期

机译：β-O-4型Dilignol化合物及其铁配合物，用于对腐殖酸的铁结合建模：合成，表征，电化学研究和藻类生长实验
4. FLUORESCENCE AND ENERGY TRANSFER PROCESSES OF HUMIC SUBSTANCES AND RELATED MODEL COMPOUNDS IN TERBIUM COMPLEXES [C] . Michael U. Kumke, Sascha Eidner Humic Substances Seminar . 2005

机译：铽复合物中腐殖质和相关模型化合物的荧光和能量转移过程
5. Photochemistry of group 8 metal complexes of type [M(bpy)2 cyanogen] (M = iron, ruthenium). Photosynthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) compounds, or, Photoassisted synthesis of heteroleptic iron(II) compounds and photoionization of ruthenium(II) complexes. [D] . Turner, David Benjamin. 2009

机译：[M（bpy）2氰基]类型的第8组金属配合物的光化学（M =铁，钌）。杂合铁（II）化合物的光合作用和钌（II）化合物的光电离，或者杂合铁（II）化合物的光辅助合成和钌（II）配合物的光电离。
6. Impact of the Oxidant Type on the Efficiency of the Oxidation and Removal of Iron Compounds from Groundwater Containing Humic Substances [O] . Izabela Krupińska 2020

机译：氧化剂型对含有腐殖质物质的地下水氧化和去除铁化合物效率的影响
7. Benzoic hydroxamate-based iron complexes as model compounds for humic substances: synthesis, characterization and algal growth experiments [O] . Orlowska, Ewelina, Institut fur Anorganische Chemie, Fakultat fur Chemie, University of Vienna, Roller, Alexander, 2016

机译：苯甲酸异羟肟酸酯基铁络合物作为腐殖质的模型化合物：合成，表征和藻类生长实验
8. Model Compound Interactions Characterizing Aquatic Humic Substances [R] . Castro, J. E. 1990

机译：表征水生腐殖质的模型化合物相互作用

Benzoic hydroxamate-based iron complexes as model compounds for humic substances: synthesis, characterization and algal growth experiments

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