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Push-pull type alkoxy-wrapped N-annulated perylenes for dye-sensitized solar cells

机译:用于染料敏化太阳能电池的推拉式烷氧基包裹的N-环状丙基

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摘要

Three push-pull type, alkoxy- wrapped N-annulated perylene based sensitizers with different electron-accepting moieties were designed and synthesized. All the three dyes exhibited broad and intense absorption in the visible region. Co(II)/(III) based dye-sensitized solar cells showed overall power conversion efficiencies up to 8.38% for QB5 under the 100 mW cm(-2), simulated AM1.5G sunlight. The detailed optical, electrochemical, photovoltaic measurements and theoretic calculations were conducted and discussed to understand the relationship between the structure and properties.
机译:三种推拉式,设计和合成了具有不同电子接受部分的基于烷氧基的烷氧基的N-Counduld的苯二苯。 所有三种染料在可见区域中表现出宽且浓度。 CO(II)/(III)染料敏化太阳能电池显示出100mM厘米(-2)下QB5的总功率转化效率高达8.38%,模拟AM1.5G阳光下。 进行详细的光学,电化学,光伏测量和理论计算,并讨论以了解结构和性质之间的关系。

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  • 来源
    《RSC Advances》 |2016年第84期|共7页
  • 作者单位

    Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

    Zhejiang Univ Dept Chem Hangzhou 310028 Zhejiang Peoples R China;

    Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

    Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

    ASTAR Inst Mat Res &

    Engn 2 Fusionopolis Way Innovis 08-03 Singapore 138634 Singapore;

    ASTAR Inst Mat Res &

    Engn 2 Fusionopolis Way Innovis 08-03 Singapore 138634 Singapore;

    Zhejiang Univ Dept Chem Hangzhou 310028 Zhejiang Peoples R China;

    Natl Univ Singapore Dept Chem 3 Sci Dr 3 Singapore 117543 Singapore;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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