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Novel PVDF hollow fiber ultrafiltration membranes with antibacterial and antifouling properties by embedding N-halamine functionalized multi-walled carbon nanotubes (MWNTs)

机译:新型PVDF中空纤维超滤膜通过嵌入N-卤素官能化的多壁碳纳米管(MWNT)来抗菌和防污性能

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摘要

Multi-walled carbon nanotubes grafted with (3-chloro-2-hydroxypropyl)-(5,5-dimethylhydantoinyl-1-ylmethyl)- dimethylammonium chloride (MWNTs-g-CDDAC) are doped in a PVDF spinning solution to prepare a kind of novel PVDF/MWNTs-g-CDDAC hollow fiber ultrafiltration membrane with antibacterial and antifouling properties. The MWNTs-g-CDDAC are firstly synthesized and characterized by FTIR, XPS and TGA. With the addition of MWNTs-g-CDDAC in the dopes, the sponge-like structure is suppressed and the finger-like macrovoids grow wider for the PVDF/MWNTs-g-CDDAC hollow fiber membranes. The surface hydrophilicity and antifouling ability of the membranes are evidently improved by introducing MWNTs-g-CDDAC onto the membranes. The pure water permeability gradually increases with the loading of MWNTs-g-CDDAC in the hybrid membranes, and the highest value of 94.7 L m(-2) bar(-1) h(-1) is obtained with 0.5 wt% MWNTs-g-CDDAC addition in the dope. The permeation flux recovery ratio (Rf) increases with the addition of MWNTs-g-CDDAC, and M-75 (0.75 wt% MWNTs-g-CDDAC loading in dope) exhibits the highest Rf value of 90.6% after two ultrafiltration-cleaning cycles for a BSA aqueous solution. The fabricated PVDF/MWNTs-g-CDDAC membranes have favorable antibacterial efficacy, and M-75 shows the utmost sterilization ratios of 92.7% and 95.2% against E. coli and S. aureus, respectively.
机译:接枝的多壁碳纳米管(3-氯-2-羟丙基) - (5,5-二甲基羟基苯基-1-基甲基) - 二甲基氯化铵(MWNTS-G-CDDAc)掺杂在PVDF纺丝溶液中以制备一种新型PVDF / MWNTS-G-CDDAC中空纤维超滤膜,具有抗菌和防污性能。首先合成MWNTS-G-CDDAC并通过FTIR,XPS和TGA表征。随着掺杂剂中的MWNTS-G-CDDAc加入,抑制海绵状结构,并且指状宏体为PVDF / MWNTS-G-CDDAC中空纤维膜较宽。通过将MWNTS-G-CDDAc引入膜上,显然改善了膜的表面亲水性和防污能力。纯净的水渗透性随着杂交膜的载荷逐渐增加,含有MWNTS-G-CDDAc的负载,最高值为94.7Lm(-2)棒(-1)H(-1),用0.5wt%MWNTS获得 - G-CDDAC添加涂料。渗透通量回收率(RF)随着添加MWNTS-G-CDDAc而增加,M-75(0.75wt%MWNTS-G-CDDAc负载掺杂)在两个超滤清洁循环后,最高的RF值为90.6%对于BSA水溶液。制造的PVDF / MWNTS-G-CDDAC膜具有良好的抗菌效力,M-75分别显示出92.7%和95.2%的最大灭菌比例,分别对大肠杆菌和金黄色葡萄球菌。

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  • 来源
    《RSC Advances》 |2016年第3期|共12页
  • 作者单位

    Shanghai Normal Univ Dept Chem &

    Chem Engn Shanghai Key Lab Rare Earth Funct Mat Educ Minist Key Lab Resource Chem Shanghai 200234 Peoples R China;

    Shanghai Normal Univ Coll Life &

    Environm Sci Shanghai 200234 Peoples R China;

    Shanghai Normal Univ Dept Chem &

    Chem Engn Shanghai Key Lab Rare Earth Funct Mat Educ Minist Key Lab Resource Chem Shanghai 200234 Peoples R China;

    Shanghai Normal Univ Dept Chem &

    Chem Engn Shanghai Key Lab Rare Earth Funct Mat Educ Minist Key Lab Resource Chem Shanghai 200234 Peoples R China;

    Shanghai Normal Univ Coll Life &

    Environm Sci Shanghai 200234 Peoples R China;

    Shanghai Normal Univ Dept Chem &

    Chem Engn Shanghai Key Lab Rare Earth Funct Mat Educ Minist Key Lab Resource Chem Shanghai 200234 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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