Efficient epoxide isomerization within a self-assembled hexameric organic capsule

Caneva Thomas; Sperni Laura; Strukul Giorgio; Scarso Alessandro

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Efficient epoxide isomerization within a self-assembled hexameric organic capsule

机译：在自组装的六聚体有机胶囊内有效环氧异构化

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The isomerization of epoxides to the corresponding carbonyl compounds is efficiently catalyzed by the supramolecular organic nano-capsule formed by the self-assembly of six resorcin[4] arene units. The capsule provides a combination of weak Bronsted acidity and a suitable nano-environment that favors the metal-free isomerization reaction.

机译：通过通过六个间聚蛋白[4]芳烃单元的自组装形成的超分子有机纳米胶囊，通过自组装形成的超分子有机纳米胶囊有效地催化环氧化物的异构化。胶囊提供弱伪造酸度和合适的纳米环境的组合，其利用无金属异构化反应。

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《RSC Advances》 |2016年第87期|共5页
作者
Caneva Thomas; Sperni Laura; Strukul Giorgio; Scarso Alessandro;
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Univ Ca Foscari Venezia Dipartimento Sci Mol &

Nanosistemi Via Torino 155 I-30172 Venice VE Italy;

Univ Ca Foscari Venezia Dipartimento Sci Mol &

Nanosistemi Via Torino 155 I-30172 Venice VE Italy;

Univ Ca Foscari Venezia Dipartimento Sci Mol &

Nanosistemi Via Torino 155 I-30172 Venice VE Italy;

Univ Ca Foscari Venezia Dipartimento Sci Mol &

Nanosistemi Via Torino 155 I-30172 Venice VE Italy;

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正文语种 eng
中图分类化学;
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1. Efficient epoxide isomerization within a self-assembled hexameric organic capsule [J] . Caneva Thomas, Sperni Laura, Strukul Giorgio, RSC Advances . 2016,第87期

机译：在自组装的六聚体有机胶囊内有效环氧异构化
2. Efficient isonitrile hydration through encapsulation within a hexameric self-assembled capsule and selective inhibition by a photo-controllable competitive guest [J] . Giulio Bianchini, Giorgio La Sorella, Nicolo Canever, Chemical Communications . 2013,第46期

机译：通过封装在六聚体自组装胶囊中并通过光控竞争性客体选择性抑制来实现高效的异腈水合
3. Encapsulation and Enhanced Luminescence Properties of Ir-III Complexes within a Hexameric Self-Assembled Capsule [J] . Horiuchi Shinnosuke, Tanaka Hirotaka, Sakuda Eri, Chemistry: A European journal . 2016,第49期

机译：六聚体自组装胶囊中Ir-III配合物的封装和增强的发光性质
4. Isomerization of epoxides to allylic alcohols catalyzed by TiO2-supported with gold nanoparticles [C] . Manolis Stratakis, Christos Raptis, Hermenehildo Garcia European Symposium on Organic Chemistry . 2009

机译：用金纳米粒子催化的TiO2催化环氧胺对烯丙基醇的异构化
5. Palladium-catalyzed isomerization of epoxides to carbonyl compounds: Scope and mechanism. [D] . Kulasegaram, Sanjitha. 1997

机译：钯催化环氧化物异构化为羰基化合物：范围和机理。
6. Hybrid inorganic-organic capsules for efficient intracellular delivery of novel siRNAs against influenza A (H1N1) virus infection [O] . Alexander S. Timin, Albert R. Muslimov, Aleksandra V. Petrova, -1

机译：杂合无机-有机胶囊可有效地在细胞内递送新型siRNA以抵抗甲型流感（H1N1）病毒感染
7. Efficient epoxide isomerization within a selfassembled\ud hexameric organic capsule [O] . Caneva, Thomas, Sperni, Laura, Strukul, Giorgio, 2016

机译：自组装\ ud内的高效环氧异构化六聚体有机胶囊

Efficient epoxide isomerization within a self-assembled hexameric organic capsule

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