A nanoscale Fe(II) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst

Li Yue; Liu Huan; Li Wen-Juan; Zhao Fang-Yao; Ruan Wen-Juan

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A nanoscale Fe(II) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst

机译：纳米级Fe（II）金属 - 有机骨架，其与双炔丙基羧酸盐配体，作为高性能的非均相FENTON催化剂

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With 2,2'-bipyridine-5,5'-dicarboxylate as the ligand, a nanoscale Fe(II) MOF material (Fe-bpydc) was synthesized. Fe-bpydc could activate H2O2 to degrade organic pollutants in near neutral conditions, and its activity and stability are superior to reported results. Interestingly, Fe-bpydc only consumes H2O2 in the presence of organics, leading to high H2O2 utilization efficiency.

机译：用2,2'-硼吡啶-5,5,5'-二羧酸酯作为配体，合成纳米级Fe（II）MOF材料（Fe-BPYDC）。 Fe-BPYDC可以激活H 2 O 2，以降解近中立条件下的有机污染物，其活性和稳定性优于报道的结果。有趣的是，Fe-Bpydc仅在有机物的存在下消耗H2O2，导致高H2O2利用效率。

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《RSC Advances》 |2016年第8期|共5页
作者
Li Yue; Liu Huan; Li Wen-Juan; Zhao Fang-Yao; Ruan Wen-Juan;
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Nankai Univ Minist Educ Dept Chem Tianjin 300071 Peoples R China;

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正文语种 eng
中图分类化学;
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1. A nanoscale Fe(II) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst [J] . Li Yue, Liu Huan, Li Wen-Juan, RSC Advances . 2016,第8期

机译：纳米级Fe（II）金属 - 有机骨架，其与双炔丙基羧酸盐配体，作为高性能的非均相FENTON催化剂
2. Fe-based metal-organic frameworks as Fenton-like catalysts for highly efficient degradation of tetracycline hydrochloride over a wide pH range: Acceleration of Fe(II)/Fe(III) cycle under visible light irradiation [J] . Wu Qiangshun, Yang Hanpei, Kang Li, Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2020,第1期

机译：Fe基金属 - 有机框架作为芬顿催化剂，用于在宽的pH范围内高效降解四环素盐酸盐，在可见光照射下加速Fe（II）/ Fe（III）循环
3. Nanoscaled Copper Metal-Organic Framework (MOF) Based on Carboxylate Ligands as an Efficient Heterogeneous Catalyst for Aerobic Epoxidation of Olefins and Oxidation of Benzylic and Allylic Alcohols [J] . Qi Yue, Luan Yi, Yu Jie, Chemistry: A European journal . 2015,第4期

机译：基于羧酸盐配体的纳米级铜金属有机骨架（MOF），作为高效多相催化剂，可进行烯烃的好氧环氧化以及氧化苯甲酸和烯丙醇
4. Impact of Inorganic Salts on Degradation of Azo Dye Using Fe (III)-modified PAN Fiber Complex as Heterogeneous Fenton Catalyst [C] . Zhichao Wang, Yongchun Dong, Siming Dong, International Conference on Manufacturing Science and Engineering . 2011

机译：无机盐对偶氮染料降解Fe（III）制型锅纤维复合物作为异质Fenton催化剂的影响
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Synthesis Characterization and Application of Iron(II) Doped Copper Ferrites (CuII(x)FeII(1-x)FeIII2O4) as Novel Heterogeneous Photo-Fenton Catalysts [O] . Asfandyar Khan, Zsolt Valicsek, Ottó Horváth 2020

机译：铁（II）掺杂铜铁氧体（CuII（x）FeII（1-x）FeIII2O4）的合成表征及应用
7. Synthesis, Characterization and Application of Iron(II) Doped Copper Ferrites (CuII(x)FeII(1-x)FeIII2O4) as Novel Heterogeneous Photo-Fenton Catalysts [O] . Asfandyar Khan, Zsolt Valicsek, Ottó Horváth 2020

机译：铁（II）掺杂铜铁氧体（Cuii（x）Feii（1-x）Feiii2O4）作为新型异质光 - Fenton催化剂的合成，表征和应用

A nanoscale Fe(II) metal-organic framework with a bipyridinedicarboxylate ligand as a high performance heterogeneous Fenton catalyst

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