A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS)

Garcia Nuria; Fernandez-Rodriguez Manuel A.; Garcia-Garcia Patricia; Pedrosa Maria R.; Arnaiz Francisco J.; Sanz Roberto

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A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS)

机译：使用3-巯基丙基官能化硅胶（MPS）的实用和化学选择性硫氧化亚氧化硫氧化物还原方案

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摘要

A convenient sulfoxide deoxygenation procedure using a mercaptopropyl-functionalized silica gel as the reducing agent is described. This new protocol based on a heterogeneous reagent displays broad scope and tolerance to reducible functional groups and, from an experimental point of view, enhances previous methods by simplifying the isolation of the sulfide to a simple filtration.

机译：描述了使用巯基丙基官能化硅胶作为还原剂的方便亚砜脱氧程序。基于异质试剂的这种新的协议显示了可降低官能团的宽范围和耐受，通过简化硫化物分离以简单过滤来增强以前的方法。

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《RSC Advances》 |2016年第32期|共4页
作者
Garcia Nuria; Fernandez-Rodriguez Manuel A.; Garcia-Garcia Patricia; Pedrosa Maria R.; Arnaiz Francisco J.; Sanz Roberto;
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作者单位

Univ Burgos Fac Ciencias Dept Quim Pza Misael Banuelos S-N Burgos 09001 Spain;

Univ Burgos Fac Ciencias Dept Quim Pza Misael Banuelos S-N Burgos 09001 Spain;

Univ Alcala De Henares Dept Quim Organ &

Quim Inorgan Madrid 28871 Spain;

Univ Burgos Fac Ciencias Dept Quim Pza Misael Banuelos S-N Burgos 09001 Spain;

Univ Burgos Fac Ciencias Dept Quim Pza Misael Banuelos S-N Burgos 09001 Spain;

Univ Burgos Fac Ciencias Dept Quim Pza Misael Banuelos S-N Burgos 09001 Spain;

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正文语种 eng
中图分类化学;
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1. A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS) [J] . Garcia Nuria, Fernandez-Rodriguez Manuel A., Garcia-Garcia Patricia, RSC Advances . 2016,第32期

机译：使用3-巯基丙基官能化硅胶（MPS）的实用和化学选择性硫氧化亚氧化硫氧化物还原方案
2. A novel, simple, chemoselective and practical protocol for the reduction of azides using In/NH4Cl [J] . Reddy GV., Iyengar DS., Rao GV. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1999,第20期

机译：一种使用In / NH4Cl还原叠氮化物的新颖，简单，化学选择性和实用的方案
3. Simple and practical protocol for the silylation of phenol derivatives using reusable NaHSO4 dispread on silica gel under neutral conditions [J] . Khalili MS, Ghafuri H, Mojahedi-Jahromi S, Phosphorus, Sulfur, and Silicon and the Related Elements . 2007,第1期

机译：使用可重复使用的NaHSO4在中性条件下分散在硅胶上的简单实用的酚衍生物硅烷化方法
4. Encapsulated Metal 'Catalysts in Siloxane Gels: Pt-Catalyzed Chemoselective Reduction of Nitro Compounds [C] . Kazuyuki Kamo, Yukihiro Motoyama, Hideo Nagashima Symposium on Organometallic Chemistry . 2008

机译：硅氧烷凝胶中的包封金属'催化剂：Pt催化的硝基化合物的化学选择性还原
5. Methionine-R-sulfoxide reductases and biological importance of free methionine sulfoxide reduction. [D] . Lee, Byung Cheon. 2010

机译：蛋氨酸-R-亚砜还原酶和游离蛋氨酸亚砜还原的生物学重要性。
6. The synthesis of controlled shape nanoplasmonic silver-silica structures by combining sol-gel technique and direct silver reduction [O] . Lina Ramanauskaite, Valentinas Snitka 2015

机译：溶胶-凝胶技术与直接银还原相结合合成可控形状的纳米等离子体银-二氧化硅结构
7. A practical and chemoselective Mo-catalysedudsulfoxide reduction protocol using a 3-udmercaptopropyl-functionalized silica gel (MPS) [O] . García Nuria, Fernández Rodríguez Manuel A., García García Patricia, 2016

机译：实用且化学选择性的Mo催化 ud使用3- ud的亚砜还原方案巯基丙基官能化的硅胶（MPS）

A practical and chemoselective Mo-catalysed sulfoxide reduction protocol using a 3-mercaptopropyl-functionalized silica gel (MPS)

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