Application of nanoparticle mediated N-arylation of amines for the synthesis of pharmaceutical entities using vit-E analogues as amphiphiles in water

Kumar Atul; Bishnoi Ajay Kumar

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Application of nanoparticle mediated N-arylation of amines for the synthesis of pharmaceutical entities using vit-E analogues as amphiphiles in water

机译：纳米粒子介导的N-芳族化胺的应用使用VIT-E类似物作为水中的两亲物质的药物实体合成

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The first CuI-nanoparticle catalyzed inter and intramolecular N-arylation of amines using vitamin E analogues (TPGS) as amphipiles has been developed in water. Application of this transition metal-amphiphile C-N bond formation methodology is further extended for the synthesis of substituted indoles, bioactive natural product tryptanthrin and intermediates of pharmaceutical entities such as imatinib, nilotinib, selective D3 agonist/antagonist ligands, and oxacarbazepine.

机译：在水中开发了使用维生素E类似物（TPG）催化胺和分子内N-芳基胺的第一种Cui-纳米粒子。这种过渡金属 - 两亲键合形成方法进一步延长了取代吲哚，生物活性天然产物Tryptanthrin和药物实体的中间体，如伊马替尼，尼洛替尼，选择性D3激动剂/拮抗剂配体和氧毒霸，以及氧达甲脂动物。

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来源
《RSC Advances》 |2015年第26期|共5页
作者
Kumar Atul; Bishnoi Ajay Kumar;
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CSIR Cent Drug Res Inst Med &

Proc Chem Div Lucknow 226031 Uttar Pradesh India;

CSIR Cent Drug Res Inst Med &

Proc Chem Div Lucknow 226031 Uttar Pradesh India;

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正文语种 eng
中图分类化学;
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1. Application of nanoparticle mediated N-arylation of amines for the synthesis of pharmaceutical entities using vit-E analogues as amphiphiles in water [J] . Kumar Atul, Bishnoi Ajay Kumar RSC Advances . 2015,第26期

机译：纳米粒子介导的N-芳族化胺的应用使用VIT-E类似物作为水中的两亲物质的药物实体合成
2. Tamarix gallica leaf extract mediated novel route for green synthesis of CuO nanoparticles and their application for N-arylation of nitrogen-containing heterocycles under ligand-free conditions [J] . Nasrollahzadeh Mahmoud, Sajadi S. Mohammad, Maham Mehdi RSC Advances . 2015,第51期

机译：Tamarix Gallica Lead提取物介导的CuO纳米粒子绿色合成的新途径及其在配体条件下的含氮杂环的N-芳基化的应用
3. High Catalytic Activity of Peptide Nanofibres Decorated with Ni and Cu Nanoparticles for the Synthesis of 5-Substituted 1H-Tetrazoles and N-Arylation of Amines [J] . Ghorbani-Choghamarani Arash, Taherinia Zahra Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2017,第10期

机译：用Ni和Cu纳米粒子装饰的肽纳米纤维的高催化活性用于合成5-取代的1H-四唑和胺的N-芳族化
4. Synthesis of Carbazole Derivatives by Palladium Catalyzed Double N-Arylation of Amines [C] . Yuko Hidehira, Koji Nakano, Atsushi Kuwahara, Symposium on Organometallic Chemistry . 2004

机译：钯催化酶衍生物的合成衍生物的双N-芳基芳基
5. Part I. Asymmetric organocatalysis: (1) Direct enantioselective organocatalytic hydroxymethylation of aldehydes catalyzed by alpha,alpha-diphenylprolinol trimethylsilyl ether: Application in the formal synthesis of (-)-Rasfonin; (2) Synthesis of a novel bicyclic secondary amine organocatalyst: Application to the direct enantioselective organocatalytic hydroxymethylation of aldehydes. Part II. Asymmetric synthesis of bicyclic analogues of the anti-osteoporotic drug risedronate. [D] . Miller, John Robert. 2010

机译：第一部分，不对称有机催化：（1）α，α-二苯基脯氨醇三甲基甲硅烷基醚催化的醛的直接对映选择性有机催化羟甲基化：在（-）-Rasfonin的正式合成中的应用；（2）新型双环仲胺有机催化剂的合成：应用于醛的直接对映选择性有机催化羟甲基化。第二部分抗骨质疏松药物Risedronate的双环类似物的不对称合成。
6. Synthesis and Application of Amine Functionalized Iron Oxide Nanoparticles on Menaquinone-7 Fermentation: A Step towards Process Intensification [O] . Alireza Ebrahiminezhad, Vikas Varma, Shuyi Yang, 2016

机译：甲萘醌7发酵中胺功能化氧化铁纳米粒子的合成与应用：工艺强化的一步
7. Gripe water-mediated green synthesis of silver nanoparticles and their applications in nonlinear optics and surface-enhanced Raman spectroscopy [O] . E. Kirubha, K. Vishista, P. K. Palanisamy 2014

机译：银纳米颗粒的水绿色介导绿色合成及其在非线性光学和表面增强拉曼光谱中的应用

Application of nanoparticle mediated N-arylation of amines for the synthesis of pharmaceutical entities using vit-E analogues as amphiphiles in water

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