Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(I) salts

Traficante Carla I.; Mata Ernesto G.; Delpiccolo Carina M. L.

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Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(I) salts

机译：非常高效且广泛的钯催化的Hiyama交叉耦合。水和铜（i）盐的作用

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A very high-yielding Pd-catalyzed cross-coupling between aryl halides and aryl(trialkoxy)silanes is achieved in the presence of Cu(I) and a measured amount of water. This novel methodology is useful for the generation of a wide range of biaryls, particularly non-para substituted derivatives, which are usually less reported.

机译：在Cu（I）的存在下，实现了芳基卤化物和芳基（三氧基）硅烷之间的非常高产生的PD催化交叉偶联和测量的水。这种新方法对于产生广泛的野生醛，特别是非对取代衍生物的产生通常较少。

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《RSC Advances》 |2015年第34期|共5页
作者
Traficante Carla I.; Mata Ernesto G.; Delpiccolo Carina M. L.;
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Univ Nacl Rosario Fac Ciencias Bioquim &

Farmaceut CONICET UNR Inst Quim Rosario RA-2000 Rosario Argentina;

Univ Nacl Rosario Fac Ciencias Bioquim &

Farmaceut CONICET UNR Inst Quim Rosario RA-2000 Rosario Argentina;

Univ Nacl Rosario Fac Ciencias Bioquim &

Farmaceut CONICET UNR Inst Quim Rosario RA-2000 Rosario Argentina;

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正文语种 eng
中图分类化学;
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1. Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(I) salts [J] . Traficante Carla I., Mata Ernesto G., Delpiccolo Carina M. L. RSC Advances . 2015,第34期

机译：非常高效且广泛的钯催化的Hiyama交叉耦合。水和铜（i）盐的作用
2. Electron-rich trialkyl-type dihydro-KITPHOS monophosphines: Efficient ligands for palladium-catalyzed suzuki-miyaura cross-coupling. Comparison with their biaryl-like KITPHOS monophosphine counterparts [J] . Doherty S., Knight J.G., Ward N.A.B., Organometallics . 2013,第6期

机译：富电子的三烷基型二氢-KITPHOS单膦：钯催化的铃木宫浦交叉偶联的高效配体。与类似联芳基的KITPHOS单膦酸酯的比较
3. Palladium-Catalyzed Hiyama Coupling of Benzylic Ammonium Salts via C-N Bond Cleavage [J] . Han Chunyu, Zhang Zhenming, Xu Silin, The Journal of Organic Chemistry . 2019,第24期

机译：钯催化苄基铵盐通过C-N键切割的Hiyama偶联
4. Controlled accumulation of inorganic salts in microreactors for palladium-catalyzed amination [C] . Yizheng Chen, Ryan L. Hartman AIChE Annual Meeting . 2014

机译：对钯催化胺化微反应器中无机盐的控制积累
5. Novel conjugated materials via zirconocene coupling and palladium-catalyzed cross-coupling. [D] . Tannaci, John Frederick. 2008

机译：通过锆茂偶联和钯催化交叉偶联的新型共轭材料。
6. Palladium-Catalyzed Hiyama Cross-Coupling of Aryltrifluorosilanes with Aryl and Heteroaryl Chlorides [O] . Gary A. Molander, Laura Iannazzo -1

机译：钯催化桧山修aryltrifluorosilanes的交叉偶联与芳基和杂氯化物
7. Tetrabutylphosphonium 4-ethoxyvalerate as a biomass-originated media for homogeneous palladium-catalyzed Hiyama coupling reactions [O] . László Orha, Ábrahám Papp, József M. Tukacs, 2020

机译：四丁基鏻4-乙氧基甲醛作为均相钯催化的HIYAMA偶联反应的生物质起源培养基

Very efficient and broad-in-scope palladium-catalyzed Hiyama cross-coupling. The role of water and copper(I) salts

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