首页> 外文期刊>RSC Advances >Facile real-time evaluation of the stability of surface charge under regular shear stress by pulsed streaming potential measurement
【24h】

Facile real-time evaluation of the stability of surface charge under regular shear stress by pulsed streaming potential measurement

机译:通过脉冲流电位测量将表面电荷稳定性的稳定性进行实时评估

获取原文
获取原文并翻译 | 示例
           

摘要

Self-assemblies of polyelectrolytes have been widely used to tailor surface charges, but their stability varies significantly due to the diverse properties of both polyelectrolytes and surfaces. Fast and reliable evaluation of the stability of the assembled layers is essential to optimize the assembling processes and select the proper working conditions. In this work, the applicability of the pulsed streaming potential measurement for real-time evaluation of stability of assembled layers was demonstrated. Polyethyleneimine (PEI) with a molecular weight of 1800 was selected as the model polyelectrolyte and the results confirmed the dependence of the stability of the assembled layers on the assembling conditions. A parameter SR, which is defined as the relative zeta potential change rate, was adopted to reflect the difference of the positively charged layer. Effect of assembling conditions, including pH, polyelectrolyte concentration and contact time, on the change of the streaming potential were evaluated based on SR values. The feasibility of the technique for the evaluation of the stability of adsorbed proteins, oligonucleotides and cells onto the formed PEI layer was also investigated and its reliability was confirmed by capillary electrophoresis.
机译:聚电解质的自组装已广泛用于量身定制表面电荷,但由于聚电解质和表面的不同性质,它们的稳定性显着变化。快速可靠地评估组装层的稳定性对于优化组装过程并选择适当的工作条件是必不可少的。在这项工作中,对脉冲流电位测量进行了实时评估组装层的稳定性的适用性。选择分子量为1800的聚乙烯亚胺(PEI)作为模型聚电解质,结果证实了组装层稳定性对组装条件的依赖性。采用参数SR,其被定义为相对Zeta电位变化率来反映带正电的层的差异。基于SR值评估组装条件,包括pH,聚电解质浓度和接触时间的效果,对流电位的变化进行评估。还研究了对吸附蛋白质,寡核苷酸和细胞稳定性的技术的可行性,并通过毛细管电泳证实了其可靠性。

著录项

  • 来源
    《RSC Advances》 |2015年第96期|共7页
  • 作者单位

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

    Lanzhou Univ State Key Lab Appl Organ Chem Key Lab Nonferrous Met Chem &

    Resources Utilizat Dept Chem Lanzhou 730000 Gansu Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号