Unexpected formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 - the first 'piano-stool' ruthenium complex bearing a secondary aminomethylphosphane ligand

Plotek Michal; Starosta Radoslaw; Komarnicka Urszula K.; Skorska-Stania Agnieszka; Stochel Grazyna; Kyziol Agnieszka; Jezowska-Bojczuk Malgorzata

首页> 外文期刊>RSC Advances >Unexpected formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 - the first 'piano-stool' ruthenium complex bearing a secondary aminomethylphosphane ligand

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Unexpected formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 - the first 'piano-stool' ruthenium complex bearing a secondary aminomethylphosphane ligand

机译：[Ru（η（5）-C5H5）的意外形成（pH {CH2N（CH2CH2）（2）O}（2））（PPH3）（2）] BF4 - 第一“钢琴”钌配合物轴承次级氨基甲基膦酰膦配体

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In this paper we report the reaction of [Ru(eta(5)-C5H5)Cl(PPh3)(2)] with P{CH2N(CH2CH2)(2)O}(3) in the presence of NaBF4, in which, apart from the Cl- substitution, an unexpected P-C bond cleavage in the tertiary phosphane is observed. It results in the formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 (1) - the first "pianostool" ruthenium complex with a secondary aminomethylphosphane ligand.

机译：在本文中，我们在NaBF4存在下，通过P {CH2N（CH2CH2）（2）○}（3）报告[Ru（4）-C5H5）Cl（PPH3）]的反应，其中除了CL-取代，观察到叔膦的意外的PC键裂解。它导致[Ru（η（5）-C5H5）的形成（pH {CH2N（CH 2 CH 2）（2）O}（2））（PPH3）（2）] BF4（1） - 第一个“钢棒”钌络合物与二级氨基甲基膦酸配体。

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来源
《RSC Advances》 |2015年第4期|共4页
作者
Plotek Michal; Starosta Radoslaw; Komarnicka Urszula K.; Skorska-Stania Agnieszka; Stochel Grazyna; Kyziol Agnieszka; Jezowska-Bojczuk Malgorzata;
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Jagiellonian Univ Fac Chem PL-30060 Krakow Poland;

Univ Wroclaw Fac Chem PL-50383 Wroclaw Poland;

Univ Wroclaw Fac Chem PL-50383 Wroclaw Poland;

Jagiellonian Univ Fac Chem PL-30060 Krakow Poland;

Jagiellonian Univ Fac Chem PL-30060 Krakow Poland;

Jagiellonian Univ Fac Chem PL-30060 Krakow Poland;

Univ Wroclaw Fac Chem PL-50383 Wroclaw Poland;

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正文语种 eng
中图分类化学;
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1. Unexpected formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 - the first "piano-stool" ruthenium complex bearing a secondary aminomethylphosphane ligand [J] . Plotek Michal, Starosta Radoslaw, Komarnicka Urszula K., RSC Advances . 2015,第4期

机译：[Ru（η（5）-C5H5）的意外形成（pH {CH2N（CH2CH2）（2）O}（2））（PPH3）（2）] BF4 - 第一“钢琴”钌配合物轴承次级氨基甲基膦酰膦配体
2. Unexpected formation of [Ru(η5-C5H5)(PH{CH2N(CH2CH2)2O}2)(PPh3)2]BF4 – the first “piano-stool” ruthenium complex bearing a secondary aminomethylphosphane ligand [J] . Micha? P?otek, Rados?aw Starosta, Urszula K. Komarnicka, RSC Advances . 2015,第4期

机译：[Ru（η5-C5H5）的意外形成（pH {CH2N（CH2CH2）2O} 2）（PPH3）2] BF4 - 第一“钢琴”钌配合物，其仲氨基甲基膦配体
3. Ru(O2CCF3)(2)(PPh3)(2) and ruthenium phosphine complexes bearing fluoroacetate ligands: synthesis, characterization and catalytic activity [J] . Hey Daniela A., Fischer Pauline J., Baratta Walter, Dalton transactions: An international journal of inorganic chemistry . 2019,第14期

机译：Ru（O2CCF3）（2）（PPH3）（2）和含氟乙酸盐配体的钌膦络合物：合成，表征和催化活性
4. Synthesis and Reactions of Ruthenium Complexes Bearing Diphosphinidenecyclobutene Ligands (DPCB-Y) [C] . Akito Hayashi, Takahiko Yoshitomi, Masaaki Okazaki Symposium on Organometallic Chemistry . 2007

机译：含二磷苯丁丁烯配体的钌配合物的合成与反应（DPCB-Y）
5. Activation of Propargylic Alcohols by Piano-Stool Ruthenium Complexes Bearing Phosphoramidite Ligands. [D] . Costin, Stephen. 2010

机译：带有亚磷酰胺配体的钢琴凳钌配合物活化丙炔醇。
6. Synthesis Reactivity and Catalytic Transfer HydrogenationActivity of Ruthenium Complexes Bearing NNN Tridentate Ligands: Influenceof the Secondary Coordination Sphere [O] . Jing Shi, Bowen Hu, Xiangyang Chen, 2017

机译：合成反应性和催化转移加氢带有NNN三齿配体的钌配合物的活性：影响二级协调领域
7. Unexpected formation of [Ru(\eta^{5}-C_{5}H_{5})(PH\{CH_{2}N(CH_{2}CH_{2})_{2}O\}_{2})(PPh_{3})_{2}]BF_{4} : the first “piano-stool” ruthenium complex bearing a secondary aminomethylphosphane ligand [O] . Płotek, Michał, Starosta, Radosław, Komarnicka, Urszula K., 2015

机译：意外地形成了[Ru（\ eta ^ {5} -C_ {5} H_ {5}）（PH \ {CH_ {2} N（CH_ {2} CH_ {2}）_ {2} O \} _ { 2}）（PPh_ {3}）_ {2}] BF_ {4}：第一个带有仲氨基甲基膦配体的“钢琴凳”钌配合物
8. Replacement of Hydrido-Ligands in Triruthenium Complexes by Triphenylphosphinegold Groups. Crystal Structures of (AuRu3-(mu-COMe)(CO)10(PPh3), (AuRu3(mu-H)2(Mu3-COMe)(CO)9(PPh3), and (Au3Ru3(mu3-COMe)(CO)9(PPh3)3). [R] . Bateman, L. W., Green, M., Mead, K. A., 1983

机译：三苯基膦基团取代三钌配合物中的氢化配体。（auRu3-（μ-COme）（CO）10（pph3），（auRu3（mu-H）2（mu3-COme）（CO）9（pph3）和（au3Ru3（mu3-COme）（CO）的晶体结构）9（ppH3）3）。

Unexpected formation of [Ru(eta(5)-C5H5)(PH{CH2N(CH2CH2)(2)O}(2))(PPh3)(2)]BF4 - the first 'piano-stool' ruthenium complex bearing a secondary aminomethylphosphane ligand

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