Reversible photo-responsive vesicle based on the complexation between an azobenzene containing molecule and alpha-cyclodextrin

Liu Jianjia; Yan Liang; Wang Jie; Li Tao; Zhao Hanqing; Li Li; Lincoln Stephen F.; Prudhomme Robert K.; Guo Xuhong

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Reversible photo-responsive vesicle based on the complexation between an azobenzene containing molecule and alpha-cyclodextrin

机译：可逆光响应囊泡，基于含偶氮苯分子和α-环糊精之间的络合

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An amphiphilic molecule (Azo-Cl) was successfully synthesized and found to be able to construct reversible spherical vesicles in water. The assembled vesicles disappeared on the addition of equimolar alpha-cyclodextrin (alpha-CD) and reformed with UV irradiation due to the exclusion of the cis-azobenzene (Azo) group from alpha-CD's hydrophobic cavity. With Vis irradiation, the vesicles were demolished again as alpha-CD combined with the Azo group again. These reversible photo-responsive vesicles based on the complexation between Azo-Cl and alpha-CD should be ideal switchable biomimetic membranes or carriers for photo-controllable release of functional matters like drugs.

机译：成功地合成两亲分子（AZO-CL），发现能够在水中构建可逆球形囊泡。组装囊泡在添加等摩尔α-环糊精（α-CD）上消失，并且由于从α-CD的疏水腔中排除Cis-偶氮苯（AZO）基团而改性UV辐射。随着VIS照射，囊泡再次被拆除，因为α-CD再次与AZO组联合。这些可逆的光响应囊泡基于Azo-Cl和α-CD之间的络合应该是可切换的仿生膜或用于可光控制释放的功能性问题的载体。

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来源
《RSC Advances》 |2015年第41期|共7页
作者
Liu Jianjia; Yan Liang; Wang Jie; Li Tao; Zhao Hanqing; Li Li; Lincoln Stephen F.; Prudhomme Robert K.; Guo Xuhong;
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作者单位

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

Univ Adelaide Sch Chem &

Phys Adelaide SA 5005 Australia;

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

Univ Adelaide Sch Chem &

Phys Adelaide SA 5005 Australia;

Princeton Univ Dept Chem Engn Princeton NJ 08544 USA;

E China Univ Sci &

Technol State Key Lab Chem Engn Shanghai 200237 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Reversible photo-responsive vesicle based on the complexation between an azobenzene containing molecule and alpha-cyclodextrin [J] . Liu Jianjia, Yan Liang, Wang Jie, RSC Advances . 2015,第41期

机译：可逆光响应囊泡，基于含偶氮苯分子和α-环糊精之间的络合
2. Reversible photo-responsive gel–sol transitions of robust organogels based on an azobenzene-containing main-chain liquid crystalline polymer [J] . Jing Wang, Qian Jiang, Xingtian Hao, RSC Advances . 2020,第7期

机译：基于含偶氮苯的主链液晶聚合物的可逆照片响应凝固凝胶溶胶转变
3. Photo-responsive reversible micelles based on azobenzene-modified poly(carbonate)s via azide-alkyne click chemistry [J] . Hu Ding, Li Yefei, Niu Yile, RSC Advances . 2014,第89期

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4. Reversible Dose-Based Drug Release Mediated by Azobenzene/α-Cyclodextrin Complexation to Study Myofibroblast Activation [C] . Eric M. Nehls, Adrianne M. Rosales, Kristi S. Anseth Society for Biomaterials annual meeting and exposition . 2015

机译：偶氮苯/α-环糊精络合介导的基于剂量的可逆药物释放，研究成肌纤维细胞活化
5. I. Toward photocontrol of kinase activity. II. Functionalized azobenzenes through cross-coupling with organotrifluoroborates. III. Regulating enzymatic activity with a photoswitchable affinity label. IV. Reversible photomechanical switching of individual engineered molecules at a metallic surface. V. Fluorescent lipid probes of potassium channel function. [D] . Harvey, Jessica Hitchcock. 2008

机译：I.对激酶活性进行光控制。二。通过与有机三氟硼酸酯交叉偶联来官能化的偶氮苯。三，用光开关亲和标记调节酶活性。 IV。金属表面上单个工程分子的可逆光机械转换。 V.钾通道功能的荧光脂质探针。
6. Synthesis of Bis-β-Diketonate Lanthanide Complexeswith an Azobenzene Bridge and Studies of Their Reversible Photo/ThermalIsomerization Properties [O] . Cai-Ye Fu, Lu Chen, Xuan Wang, 2019

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7. Reversible photo-responsive gel–sol transitions of robust organogels based on an azobenzene-containing main-chain liquid crystalline polymer [O] . Jing Wang, Qian Jiang, Xingtian Hao, 2020

机译：基于含偶氮苯的主链液晶聚合物的可逆照片响应凝固凝胶溶胶转变
8. Azo Polymers for Reversible Optical Storage. 5. Orientation and DipolarInteractions of Azobenzene Side Groups in Copolymers and Blends Containing Methyl Methacrylate Structural Units [R] . Brown, D., Natansohn, A., Rochon, P. 1995

机译：用于可逆光存储的偶氮聚合物。 5.含有甲基丙烯酸甲酯结构单元的共聚物和共混物中偶氮苯侧基的取向和偶极相互作用

Reversible photo-responsive vesicle based on the complexation between an azobenzene containing molecule and alpha-cyclodextrin

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