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High performance epoxy protective coatings incorporated with polyaniline nanowires using cardanol-based phenalkamine as the curing agent

机译:使用基于Cardanol的苯胺作为固化剂,加入高性能环氧保护涂料与聚苯胺纳米线掺入

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摘要

To investigate the performance of cardanol-based phenalkamine as curing agent, epoxy protective coatings were prepared. Different weight contents of polyaniline nanowires were also incorporated to improve the protective performance of the coatings. The wettability and the adhesion strength of the coatings were investigated. The prepared coatings were tested by immersing the samples in 12 wt% NaCl solution at 95 degrees C and the electrochemical impedance spectroscopy technique was used to evaluate the performance of the coatings. The experimental results indicate that the epoxy protective coatings cured by cardanol-based phenalkamine provide excellent protection for mild carbon steel. The coating containing 2 wt% polyaniline nanowires exhibits the best corrosion resistance performance and its impedance modulus at 0.01 Hz is close to 1 x 10(11) Ohm cm(2) after 60 days of immersion. The passive properties of polyaniline nanowires were characterized by scanning electron microscopy and X-ray photoelectron spectroscopy.
机译:为了研究基于腰果酚酚醛胺的性能作为固化剂,制备环氧树脂的保护涂层。聚苯胺纳米线的不同重量内容也纳入来改善涂层的防护性能。润湿性和涂层的粘结强度的影响。将制得的涂料通过在95℃和所使用的电化学阻抗谱技术来评估涂层的性能浸渍的样品中12重量%的NaCl溶液进行测试。实验结果表明,通过基于腰果酚酚醛胺固化环氧树脂的保护涂层提供低碳钢极好的保护。含有涂料2重量%的纳米线的聚苯胺呈现最好的耐腐蚀性的性能和它的阻抗模量在0.01Hz靠近浸渍后60天至1×10(11)欧姆厘米(2)。通过扫描电子显微镜和X射线光电子能谱聚苯胺纳米线的被动性质进行表征。

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  • 来源
    《RSC Advances》 |2015年第15期|共7页
  • 作者单位

    Tianjin Univ Sch Chem Engn &

    Technol Chem Engn Res Ctr Tianjin 300072 Peoples R China;

    Tianjin Univ Sch Chem Engn &

    Technol Chem Engn Res Ctr Tianjin 300072 Peoples R China;

    Tianjin Univ Sch Chem Engn &

    Technol Chem Engn Res Ctr Tianjin 300072 Peoples R China;

    Tianjin Univ Sch Chem Engn &

    Technol Chem Engn Res Ctr Tianjin 300072 Peoples R China;

    Tianjin Univ Sch Chem Engn &

    Technol Chem Engn Res Ctr Tianjin 300072 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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