High and selective sorption of C-2 hydrocarbons in heterometal-organic frameworks built from tetrahedral units

Tan Yan-Xi; He Yan-Ping; Zhang Jian

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High and selective sorption of C-2 hydrocarbons in heterometal-organic frameworks built from tetrahedral units

机译：在四面体单位内建造的异常 - 有机框架中C-2烃的高和选择性吸附

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Alternate connection of tetrahedral [In(COO)(4)](-) and [AgN4](+) (or [CuN4](+)) units via nicotinate ligands leads to the formation of two metal-organic frameworks (MOFs) based on packing layers. The activated framework shows high C-2 hydrocarbons (C(2)s) uptake and high selectivities of C(2)s/CH4.

机译：通过烟酸配体通过烟酸配体的四面体[in（COO）（4）（4）（4）（4）（ - ）和[AgN4]（+））单元的替代连接导致基于两种金属 - 有机框架（MOF）的形成包装层。活化框架显示出高C-2烃（C（2）S）摄取和高选择性C（2）S / CH4。

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《RSC Advances》 |2015年第10期|共4页
作者
Tan Yan-Xi; He Yan-Ping; Zhang Jian;
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Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

Chinese Acad Sci Fujian Inst Res Struct Matter State Key Lab Struct Chem Fuzhou 350002 Fujian Peoples R China;

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正文语种 eng
中图分类化学;
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1. High and selective sorption of C-2 hydrocarbons in heterometal-organic frameworks built from tetrahedral units [J] . Tan Yan-Xi, He Yan-Ping, Zhang Jian RSC Advances . 2015,第10期

机译：在四面体单位内建造的异常 - 有机框架中C-2烃的高和选择性吸附
2. Microporous metal-organic layer built from pentanuclear tetrahedral units: gas sorption and magnetism [J] . Yan-Xi Tan, Ying Zhang, Yan-Ping He New Journal of Chemistry . 2014,第11期

机译：由五核四面体单元构建的微孔金属有机层：气体吸附和磁性
3. Multifunctional Anionic MOF Material for Dye Enrichment and Selective Sorption of C-2 Hydrocarbons over Methane via Ag+-Exchange [J] . Tan Yan-Xi, Zhang Ying, He Yan-Ping, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第24期

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5. Sorption of synthetic aromatic anions onto polymeric ion exchangers: Genesis of selectivity and effects of equilibrium process variables on sorption kinetics. [D] . Li, Ping. 2000

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8. Characterization and Analysis of Devonian Shales as Related to Release of Gaseous Hydrocarbons: Well C-2 Lincoln County, West Virginia [R] . Kalyoncu, R. S., Snyder, M. J. 1979

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High and selective sorption of C-2 hydrocarbons in heterometal-organic frameworks built from tetrahedral units

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