Direct access to pyrimidines through organocatalytic inverse-electron-demand Diels-Alder reaction of ketones with 1,3,5-triazine

Yang Gongming; Jia Qianfa; Chen Lei; Du Zhiyun; Wang Jian

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Direct access to pyrimidines through organocatalytic inverse-electron-demand Diels-Alder reaction of ketones with 1,3,5-triazine

机译：通过有机催化反馈DIELS-Alder酮与酮的直接进入嘧啶，酮与1,3,5-三嗪

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An organocatalytic inverse-electron-demand Diels-Alder reaction of ketones with 1,3,5-triazine through enamine catalysis has been developed. This method could furnish 4,5-disubstituted pyrimidines in good yields and high levels of regioselectivities.

机译：已经开发了通过烯胺催化的有机催化反应酮与1,3,5-三嗪的反应。该方法可以以良好的产率和高水平的区域选择提供4,5-二取代的嘧啶。

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《RSC Advances》 |2015年第94期|共5页
作者
Yang Gongming; Jia Qianfa; Chen Lei; Du Zhiyun; Wang Jian;
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作者单位

Guangdong Univ Technol Allan H Conney Lab Anticanc Res Guangdong 510006 Peoples R China;

Guangdong Univ Technol Allan H Conney Lab Anticanc Res Guangdong 510006 Peoples R China;

Guangdong Univ Technol Allan H Conney Lab Anticanc Res Guangdong 510006 Peoples R China;

Guangdong Univ Technol Allan H Conney Lab Anticanc Res Guangdong 510006 Peoples R China;

Guangdong Univ Technol Allan H Conney Lab Anticanc Res Guangdong 510006 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Direct access to pyrimidines through organocatalytic inverse-electron-demand Diels-Alder reaction of ketones with 1,3,5-triazine [J] . Yang Gongming, Jia Qianfa, Chen Lei, RSC Advances . 2015,第94期

机译：通过有机催化反馈DIELS-Alder酮与酮的直接进入嘧啶，酮与1,3,5-三嗪
2. Synthesis of Electron-Deficient 1,3,5-Triazines as Potential Azadienes for Inverse-Electron-Demand Diels-Alder Reactions [J] . Xu GX, Zheng LY, Wang SX, Synthetic Communications . 2010,第1a3期

机译：缺电子的1,3,5-三嗪作为潜在的氮杂二烯，用于反电子需求的Diels-Alder反应
3. An efficient entry to furo[2,3-d]pyrimidines via inverse electron demand Diels-Alder reactions of 2-aminofurans with 1,3,5-triazines [J] . Qun Dang, Yan Liu Inorganic Chemistry Communications . 2009,第11期

机译：通过2-氨基呋喃与1,3,5-三嗪的反电子需量Diels-Alder反应有效地进入呋喃并[2,3-d]嘧啶
4. BIOLOGICAL AND ABIOTIC REACTIONS WITH IRON AND ELECTRON SHUTTLES THAT PROMOTE HEXAHYDRO-1,3,5-TRINITRO-1,3,5-TRIAZINE (RDX) DEGRADATION [C] . Kevin T. Finneran American Chemical Society Division of Environmental Chemistry Symposium . 2008

机译：用钢铁和电子穿梭的生物和非生物反应，促进六羟基-1,3,5-三腈-1,3,5-三嗪（RDX）降解
5. Exploration of the inverse-electron-demand Diels-Alder (IEDDA) reaction. Rapid access to benzocoumarins via IEDDA-driven domino reactions of coumarin-fused electron-deficient dienes with electron-rich dienophiles. [D] . Pottie, Ian R. 2003

机译：逆电子需求Diels-Alder（IEDDA）反应的探索。通过IEDDA驱动的香豆素融合的电子缺陷二烯与富电子的亲二烯体的多米诺反应，可快速获得苯并香豆素。
6. A Direct Route to 66’-Disubstituted-22’-Bipyridines by Double Diels-Alder/retro Diels-Alder Reaction of 55’-bi-124-Triazines [O] . Danuta Branowska 2005

机译：55-bi-124-三嗪的双Diels-Alder /复古Diels-Alder反应直接生成66-Di取代的22-联吡啶
7. Intramolecular Inverse-Electron-Demand Diels-Alder Reactions of Imidazoles with 1, 2, 4-Triazines: A New Route to 1, 2, 3, 4-Tetrahydro-1, 5-naphthyridines and Related Heterocycles [O] . -1

机译：咪唑与1,2,4-三嗪的咪唑的分子内反应 - 咪唑的反应：新途径至1,2,3,4-四氢-1,5-萘啶和相关杂环
8. Formation of the Protonated Dimer of Hexahydro-1,3,5-trinitro-1,3,5-triazine by Complex Switching Reactions [R] . Doyle, R. J., Campana, J. E., Eyler, J. R. 1985

机译：通过复合开关反应形成六氢-1,3,5-三硝基-1,3,5-三嗪的质子化二聚体

Direct access to pyrimidines through organocatalytic inverse-electron-demand Diels-Alder reaction of ketones with 1,3,5-triazine

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