Fluorescent metal-organic framework based on pyrene chromophore for sensing of nitrobenzene

Xie Shuilin; Wang Haifeng; Liu Zhonghua; Dai Renke; Huang Lizhen

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Fluorescent metal-organic framework based on pyrene chromophore for sensing of nitrobenzene

机译：基于芘发色团的荧光金属 - 有机框架，用于感应硝基苯

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A highly luminescent metal-organic framework (MOF) constructed by a rare dendritic multicarboxyl acid with a pyrene chromophore was synthesized successfully. The fluorescence intensity of the MOF in DMF is obviously stronger than that in other common solvents such as acetone, CH2Cl2, CHCl3, cyclohexane, toluene, pyridine and THF. This particular fluorescence response to DMF is significant in sensing DMF. In addition, this MOF can sense nitrobenzene effectively. Low detection limit and good reproducibility make this material promising for explosive substance detection.

机译：成功地合成由罕见的树突式多羧酸构成的高发光金属 - 有机框架（MOF），成功地合成了芘发色团。 DMF中MOF的荧光强度明显强于其他常见溶剂，例如丙酮，CH 2 Cl 2，CHCl 3，环己烷，甲苯，吡啶和THF。对DMF的这种特殊的荧光反应在感测DMF中是显着的。此外，这种MOF可以有效地感测硝基苯。低检测极限和良好的再现性使得这种材料对爆炸性物质检测有望。

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《RSC Advances》 |2015年第10期|共4页
作者
Xie Shuilin; Wang Haifeng; Liu Zhonghua; Dai Renke; Huang Lizhen;
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作者单位

S China Univ Technol Sch Biosci &

Biotechnol Guangzhou 510006 Guangdong Peoples R China;

S China Univ Technol Sch Biosci &

Biotechnol Guangzhou 510006 Guangdong Peoples R China;

Zhongshan City Peoples Hosp Dept Neurol Zhongshan 528403 Peoples R China;

S China Univ Technol Sch Biosci &

Biotechnol Guangzhou 510006 Guangdong Peoples R China;

S China Univ Technol Sch Biosci &

Biotechnol Guangzhou 510006 Guangdong Peoples R China;

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正文语种 eng
中图分类化学;
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1. Fluorescent metal-organic framework based on pyrene chromophore for sensing of nitrobenzene [J] . Xie Shuilin, Wang Haifeng, Liu Zhonghua, RSC Advances . 2015,第10期

机译：基于芘发色团的荧光金属 - 有机框架，用于感应硝基苯
2. A new three-dimensional zinc-based metal-organic framework as a fluorescent sensor for detection of cadmium ion and nitrobenzene [J] . Pan Yanan, Wang Jundong, Guo Xiumei, Journal of Colloid and Interface Science . 2018,第期

机译：一种新的三维锌基金属框架作为用于检测镉离子和硝基苯的荧光传感器
3. Tetrazine Chromophore-Based Metal-Organic Frameworks with Unusual Configurations: Synthetic, Structural, Theoretical, Fluorescent, and Nonlinear Optical Studies [J] . Li Jianghua, Jia Ding, Meng Suci, Chemistry: A European journal . 2015,第21期

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6. Tunable Two-color Luminescence and Host–guest Energy Transfer of Fluorescent Chromophores Encapsulated in Metal-Organic Frameworks [O] . Dongpeng Yan, Yanqun Tang, Heyang Lin, -1

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7. Tetrazine Chromophore-Based Metal-Organic Frameworks with Unusual Configurations: Synthetic, Structural, Theoretical, Fluorescent, and Nonlinear Optical Studies [O] . Jianghua Li, Ding Jia, Suci Meng, 2015

机译：基于四嗪发色团的金属有机框架，具有异常配置：合成，结构，理论，荧光和非线性光学研究

Fluorescent metal-organic framework based on pyrene chromophore for sensing of nitrobenzene

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