Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO2 catalyst: prospects for continuous production of energy-rich gaseous mixtures

Crnivec I. G. Osojnik; Djinovic P.; Erjavec B.; Pintar A.

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Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO2 catalyst: prospects for continuous production of energy-rich gaseous mixtures

机译：Ru / TiO2催化剂的甲型和乙酸的低温催化脱羧剂：连续生产能量丰富的气态混合物的前景

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Catalytic decarboxylation is a novel and promising pathway for continuous and efficient conversion of organic wastewaters. Stable conversion of acetic acid to CH4 and CO2 mixtures (T >= 225 degrees C, S-p > 80%, 70 h TOS) was demonstrated. Approaches for overcoming catalyst deactivation during production of H-2-rich gas from formic acid are outlined.

机译：催化脱羧是一种新颖和有前途的途径，用于连续和有效地转化有机废水。对CH 4和CO 2混合物的稳定转化为CH 4和CO 2混合物（T> = 225℃，S-P> 80％，70h TOS）。概述了克服来自富含甲酸的H-2富含H-2的富含H-2的富含催化剂失活的方法。

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《RSC Advances》 |2015年第67期|共5页
作者
Crnivec I. G. Osojnik; Djinovic P.; Erjavec B.; Pintar A.;
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Natl Inst Chem Lab Environm Sci &

Engn SI-1001 Ljubljana Slovenia;

Natl Inst Chem Lab Environm Sci &

Engn SI-1001 Ljubljana Slovenia;

Natl Inst Chem Lab Environm Sci &

Engn SI-1001 Ljubljana Slovenia;

Natl Inst Chem Lab Environm Sci &

Engn SI-1001 Ljubljana Slovenia;

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中图分类化学;
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1. Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO2 catalyst: prospects for continuous production of energy-rich gaseous mixtures [J] . Crnivec I. G. Osojnik, Djinovic P., Erjavec B., RSC Advances . 2015,第67期

机译：Ru / TiO2催化剂的甲型和乙酸的低温催化脱羧剂：连续生产能量丰富的气态混合物的前景
2. Aqueous phase reforming of ethanol and acetic acid over TiO2 supported Ru catalysts [J] . Toshiaki Nozawa, Yuichi Mizukoshi, Akihiro Yoshida Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications . 2014,第Null期

机译：TiO2负载Ru催化剂上乙醇和乙酸的水相重整。
3. Continuous hydrogen production by sequential catalytic cracking of acetic acid Part II. Mechanistic features and characterisation of catalysts under redox cycling [J] . Thomas Davidian, Nolven Guilhaume, Helene Provendier Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2008,第2期

机译：通过乙酸的连续催化裂化连续制氢（第二部分）。氧化还原循环下催化剂的力学特性和表征
4. Catalytic Hydrogenation of Aqueous Acetic Acid obtained by Fermentation into Bioethanol over Ti02-supported Ru-Sn and Ni-Sn Catalysts [C] . Luthfiana N HIDAYATI, Yuanyuan ZHAO, Eiji MINAMI 日本エネルギー学会大会 . 2019

机译：通过在TiO 2 - 负载的Ru-Sn和Ni-Sn催化剂上发酵成生物乙醇中的乙酸水溶液催化加氢
5. Process investigation and optimization of heterogeneous catalystic decarboxylation of fatty acids and fatty acid methyl esters for renewable diesel production. [D] . Wang, Dongyun. 2014

机译：用于可再生柴油生产的脂肪酸和脂肪酸甲酯非均相催化脱羧的工艺研究和优化。
6. A Novel One-Step Hydrothermal Preparation of Ru/SnxTi1−xO2 Diesel Oxidation Catalysts and its Low-Temperature Performance [O] . Li Fan, Qi Sun, Wei Zheng, 2020

机译：Ru / SnxTi1-xO2柴油氧化催化剂的一步法水热制备及其低温性能
7. Catalytic Steam Reforming of Biomass-Derived Acetic Acid over Two Supported Ni Catalysts for Hydrogen-Rich Syngas Production [O] . Peng Fu, Andong Zhang, Shan Luo, 2019

机译：两种负载型Ni催化剂的生物质衍生乙酸的催化蒸汽重整 - 富含氢的合成气产量
8. Au/MnO(x) Catalytic Performance Characteristics for Low-Temperature CO Oxidation. Effect of CO2 on the Performance of Au/MnO(x) and Pt/SnO(x) Low-Temperature CO Oxidation Catalysts [R] . Hoflund, Gar B. 1996

机译：au / mnO（x）催化低温CO氧化的性能特征。 CO2对au / mnO（x）和pt / snO（x）低温CO氧化催化剂性能的影响

Low-temperature catalytic decarboxylation of formic and acetic acid over a Ru/TiO2 catalyst: prospects for continuous production of energy-rich gaseous mixtures

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