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Emission properties of dye-doped cationic nanoparticles: size, surfactant and monomeric composition effects

机译:染料掺杂阳离子纳米粒子的排放性能:尺寸,表面活性剂和单体组成作用

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Cationic nanoparticles (NPs) demonstrate advantages over similar anionic systems in relevant applications such as nanocarriers and biomarkers. To harness their unique properties and full potential in bioimaging, a clear understanding of the factors controlling the emission performance of dye-doped cationic NPs, especially under drastic pumping conditions such as those involved in high-resolution microscopy, is required. Herein, we present, for the first time, a comprehensive analysis of the photophysical and laser properties of Rhodamine 6G (Rh6G) doped cationic NPs in colloidal suspensions and self-assembled monoliths. Composition and morphological parameters such as dye content, weigh proportion of NPs in the solution, NPs size, dielectric constant of the surrounding medium, monomeric composition, and surfactant structure, have been mapped. The fluorescence capacity of Rh6G is mainly ruled by the size of the NP, as well as by its monomer and surfactant composition. The laser properties are more sensitive to compositional changes, since laser efficiencies ranging from 50% to 0% (no lasing) are measured. Hence, a most careful selection of monomers and surfactants must be carried out in order to boost their emission and photonic properties.
机译:阳离子纳米颗粒(NPS)在如纳米载体和生物标志物如纳米载体和生物标志物如纳米载体和生物标志物中展示了与相似的阴离子系统相似的优点。为了利用其独特的性质和生物分析的全部潜力,需要清楚地了解控制染料掺杂阳离子NPS的排放性能的因素,特别是在诸如高分辨率显微镜的诸如涉及高分辨率显微镜的泵送条件下。在此,我们首次出示罗丹明6G(RH6G)掺杂胶体悬浮液中的光物理和激光特性的综合分析,以及在胶体悬架中的掺杂阳离子NP和自组装的整料。组合物和形态学参数如染料含量,溶液中NPS的重量比例,NPS尺寸,周围介质,单体组合物和表面活性剂结构的介电常数。 RH6G的荧光容量主要由NP的大小以及其单体和表面活性剂组合物统治。激光特性对组成变化更敏感,因为测量了50%至0%(无激光)的激光效率。因此,必须进行最仔细的单体和表面活性剂选择以促进它们的发射和光子性能。

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