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Multi-walled carbon nanotubes composited with nanomagnetite for anodes in lithium ion batteries

机译:用纳米磁石组成的多壁碳纳米管用于锂离子电池中的阳极

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摘要

In this work, multi-walled carbon nanotube (MWNT) nanocomposites with homogenously anchored nanomagnetite of 10-20 nm prepared by a hydrothermal-annealing method have been demonstrated to serve as anode materials for lithium ion batteries (LIBs) with a specific capacity of 829 mA h g(-1) after 50 cycles at a current density of 100 mA g(-1) and a reversible capacity of 686 mA h g(-1) at a current density of 200 mA g(-1) for the nanocomposites with a weight ratio of 1 : 1, much larger than the specific capacity of 230 mA h g(-1) after 50 cycles at a current density of 100 mA g(-1) and a reversible capacity of 195 mA h g(-1) at a current density of 200 mA g(-1) for the MWNTs. The MWNTs in the nanocomposites could efficiently buffer the strain of volume change during lithiation/delithiation and greatly improve the electrical conductivity of the electrodes. The superior electrochemical performances of the Fe3O4/MWNTs were found to originate from the unique conductive network of the MWNTs in the nanocomposites as well as the high capacity from the nanomagnetite.
机译:在这项工作中,已经证明,通过热回火方法制备的10-20nm的均匀锚固纳米磁铁(MWNT)纳米复合物的多壁碳纳米管(MWNT)纳米复合材料用作锂离子电池(LIBS)的阳极材料,其特定容量为829 Ma Hg(-1)在50次循环以100mA g(-1)的循环和686mA Hg(-1)的可逆容量,其电流密度为纳米复合材料重量比为1:1,比在电流密度为100 mA g(-1)的50次循环后的230 mA hg(-1)的比容量大于50 mA hg(-1)的比率,并且在a的可逆容量为195 ma hg(-1)用于MWNT的电流密度为200 mA g(-1)。纳米复合材料中的MWNT可以有效地缓冲锂化/脱锂期间体积变化的应变,并大大提高电极的导电性。发现Fe3O4 / mWnts的卓越电化学性能源自纳米复合材料中的MWNT的独特导电网络以及纳米磁石的高容量。

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  • 来源
    《RSC Advances》 |2015年第10期|共8页
  • 作者单位

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Tongji Univ Dept Chem Shanghai 200092 Peoples R China;

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Lamar Univ Dan F Smith Dept Chem Engn ICL Beaumont TX 77710 USA;

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Shandong Univ Minist Educ Key Lab Liquid Solid Struct Evolut &

    Proc Mat Jinan 250061 Shandong Peoples R China;

    Lamar Univ Dan F Smith Dept Chem Engn ICL Beaumont TX 77710 USA;

    Lamar Univ Dan F Smith Dept Chem Engn ICL Beaumont TX 77710 USA;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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