New structural topologies in 4f-metal cluster chemistry from vertex-sharing butterfly units: {Ln(7)(III)} complexes exhibiting slow magnetization relaxation and ligand-centred emissions

Mazarakioti Eleni C.; Cunha-Silva Luis; Bekiari Vlasoula; Escuer Albert; Stamatatos Theocharis C.

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New structural topologies in 4f-metal cluster chemistry from vertex-sharing butterfly units: {Ln(7)(III)} complexes exhibiting slow magnetization relaxation and ligand-centred emissions

机译：来自顶点共享蝴蝶单元的4F-Metal Cluster Chemistry中的新结构拓扑：{LN（7）（iii）}复合物，展示慢磁化松弛和配体中心排放

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The employment of N-salicylidene-o-aminophenol in 4f-metal cluster chemistry has led to a family of {Ln(7)} clusters with a new core topology that comprises two {Ln(4)} butterflies sharing a common metal vertex; the {Dy-7} derivative exhibits slow magnetization relaxation whereas all heptanuclear compounds show ligand-centred blue-green emissions.

机译：在4F-金属簇化学中的N-水杨酰基-O-氨基酚的就业已经导致了一个{Ln（7）}簇的家庭，其具有新的核心拓扑，其包括共享普通金属顶点的两个{Ln（4）}蝴蝶; {DY-7}衍生物表现出慢磁化松弛，而所有庚酰核化合物都显示出居性为中心的蓝绿色排放。

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《RSC Advances》 |2015年第112期|共5页
作者
Mazarakioti Eleni C.; Cunha-Silva Luis; Bekiari Vlasoula; Escuer Albert; Stamatatos Theocharis C.;
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Brock Univ Dept Chem St Catharines ON L2S 3A1 Canada;

Univ Porto Fac Sci REQUIMTE LAQV P-4169007 Oporto Portugal;

Technol Educ Inst Western Greece Dept Aquaculture &

Fisheries Management Mesolongion 30200 Greece;

Univ Barcelona Dept Quim Inorgan Inst Nanociencia &

Nanotecnol IN2UB E-08028 Barcelona Spain;

Brock Univ Dept Chem St Catharines ON L2S 3A1 Canada;

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1. New structural topologies in 4f-metal cluster chemistry from vertex-sharing butterfly units: {Ln(7)(III)} complexes exhibiting slow magnetization relaxation and ligand-centred emissions [J] . Mazarakioti Eleni C., Cunha-Silva Luis, Bekiari Vlasoula, RSC Advances . 2015,第112期

机译：来自顶点共享蝴蝶单元的4F-Metal Cluster Chemistry中的新结构拓扑：{LN（7）（iii）}复合物，展示慢磁化松弛和配体中心排放
2. Two Lanthanide(III)-Copper(II) Organic Frameworks Based on {OLn_6} Clusters that Exhibited a Large Magnetocaloric Effect and Slow Relaxation of the Magnetization [J] . Yanmin Bing, Na Xu, Wei Shi, Chemistry, an Asian journal . 2013,第7期

机译：基于{OLn_6}团簇的两个镧系元素（III）-铜（II）有机骨架，表现出较大的磁热效应和磁化作用的缓慢弛豫
3. Assembly of heterobimetallic Ni~(II)-Ln~(III) (Ln~(III) = Dy~(III), Tb~(III), Gd~(III), Ho~(III), Er~(III), Y~(III)) complexes using a ferrocene ligand: slow relaxation of the magnetization in Dy~(III), Tb~(III) and Ho~(III) analogues [J] . Amit Chakraborty, Prasenjit Bag, Eric Rivière, Dalton transactions: An international journal of inorganic chemistry . 2014,第23期

机译：异双金属Ni〜（II）-Ln〜（III）的组装（Ln〜（III）= Dy〜（III），Tb〜（III），Gd〜（III），Ho〜（III），Er〜（III）二茂铁配体形成的Y，（Y〜（III））配合物：Dy〜（III），Tb〜（III）和Ho〜（III）类似物中磁化的缓慢弛豫
4. 4f-Metal Clusters Exhibiting Slow Relaxation of Magnetization: A {Dy7} Complex with An Hourglass-like Metal Topology [O] . Konstantinos N. Pantelis, Panagiota S. Perlepe, Spyridon Grammatikopoulos, 2020

机译：表现出磁化缓慢弛豫的4f金属簇：具有沙漏状金属拓扑的{Dy7}复合物
5. 4f-Metal Clusters Exhibiting Slow Relaxation of Magnetization: A {Dy7} Complex with An Hourglass-like Metal Topology [O] . Konstantinos N. Pantelis, Panagiota S. Perlepe, Spyridon Grammatikopoulos, 2020

机译：4F-金属簇表现出磁化缓慢的宽松：{DY7}复合物，具有沙漏状金属拓扑

New structural topologies in 4f-metal cluster chemistry from vertex-sharing butterfly units: {Ln(7)(III)} complexes exhibiting slow magnetization relaxation and ligand-centred emissions

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