Novel solution-processible small molecules based on benzo[1,2-b:3,4-b ':5,6-b '']trithiophene for effective organic photovoltaics with high open-circuit voltage

Meng Lucheng; Wu Fen; Liu Hailu; Zhao Bin; Zhang Jian; Zhong Juan; Pei Yong; Chen Huajie; Tan Songting

首页> 外文期刊>RSC Advances >Novel solution-processible small molecules based on benzo[1,2-b:3,4-b ':5,6-b '']trithiophene for effective organic photovoltaics with high open-circuit voltage

【24h】

Novel solution-processible small molecules based on benzo[1,2-b:3,4-b ':5,6-b '']trithiophene for effective organic photovoltaics with high open-circuit voltage

机译：基于苯并的新型溶液 - 加工的小分子[1,2-B：3,4-B'：5,6-B'']用于具有高开路电压的有效有机光伏的三曲蛋白

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Two novel A-D-A small molecules D1 and D2, containing benzo[1,2-b:3,4-b':5,6-b ''] trithiophene as the central electron-donating unit, 3-ethylrhodanine as end-capped electron-withdrawing units, and two thiophenes or three thiophenes as conjugated pi-bridges, were designed and synthesized. The effects of the conjugated pi-bridges on the photophysical, electrochemical and photovoltaic properties as well as the aggregation structure, were fully investigated. Compared with D2, D1 shows stronger packing capability, deeper HOMO energy levels, higher hole mobility, and more appropriate microphase separation with the fullerene derivative [6,6]-phenyl-C-61-butyric acid methyl ester (PC61BM), which lead to better photovoltaic performance with higher short-circuit current density (J(sc)) and open-circuit voltages (V-oc). Bulk-heterojunction (BHJ) organic photovoltaic (OPV) devices were fabricated using a blend of the as-synthesized small molecules and PC61BM in different solvents. The D1-CF device prepared from chloroform solution with a weight ratio of 1 : 0.5 exhibited a power conversion efficiency (PCE) of 2.10% and an amazingly high V-oc of 1.10 V under AM 1.5G (100 mW cm(-2)) illumination.

机译：两种新型ADA小分子D1和D2，含有苯并[1,2-B：3,4-B'：5,6-B '']三噻吩为中心的给电子单元，3- ethylrhodanine作为封端的电子吸电子单元，和两个噻吩或噻吩3作为共轭的π桥梁，设计并合成。在光物理，电化学和光伏特性以及聚集结构的共轭的π桥的影响，进行了充分的调查。与D2，D1示出了更强的包装能力，更深的HOMO能级，更高的空穴迁移率，并且与富勒烯衍生物[6,6] - 苯基C-61 - 丁酸甲酯（PC 61 BM），其铅更适当的微相分离相比以更高的短路电流密度（j（SC））和开路电压（V-α）较好的光电性能。体异质结（BHJ）有机光伏（OPV）器件，使用的共混物制造的合成后原样的在不同溶剂中的小分子和PC61BM。的D1-CF设备从氯仿溶液制备以1:1的重量比：0.5表现出2.10％的功率转换效率（PCE）和1.10的V在AM1.5G一个令人惊讶的高V-OC（100毫瓦厘米（-2））照明。

著录项

来源
《RSC Advances》 |2015年第19期|共7页
作者
Meng Lucheng; Wu Fen; Liu Hailu; Zhao Bin; Zhang Jian; Zhong Juan; Pei Yong; Chen Huajie; Tan Songting;
展开▼
作者单位

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Guilin Univ Elect Technol Dept Mat Sci &

Engn Guilin 541004 Peoples R China;

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Xiangtan Univ Coll Chem Xiangtan 411105 Hunan Peoples R China;

Xiangtan Univ Key Lab Adv Funct Polymer Mat Coll Hunan Prov Xiangtan 411105 Peoples R China;

Xiangtan Univ Key Lab Adv Funct Polymer Mat Coll Hunan Prov Xiangtan 411105 Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Novel solution-processible small molecules based on benzo[1,2-b:3,4-b ':5,6-b '']trithiophene for effective organic photovoltaics with high open-circuit voltage [J] . Meng Lucheng, Wu Fen, Liu Hailu, RSC Advances . 2015,第19期

机译：基于苯并的新型溶液 - 加工的小分子[1,2-B：3,4-B'：5,6-B'']用于具有高开路电压的有效有机光伏的三曲蛋白
2. Synthesis and photovoltaic investigation of dithieno[2,3-d:2 ',3 '-d ']-benzo[1,2-b:3,4-b ':5,6-d '']trithiophene-based conjugated polymer with an enlarged pi-conjugated system [J] . Zhang Xiaofang, Zhang Minjing, Tong Junfeng, Polymers for advanced technologies . 2019,第5期

机译：二噻吩的合成和光伏调查[2,3-D：2'，3'-D'] - 苯并[1,2-B：3,4-B'：5,6-D''基于三苯丙胺的共轭具有扩大的PI缀合系统的聚合物
3. Synthesis, optical and electrochemical properties new donor-acceptor (D-A) copolymers based on benzo [1,2-b:3,4-b':6,5-b"] trithiophene donor and different acceptor units: Application as donor for photovoltaic devices [J] . M.L Keshtov, Y.Geng, S.A.Kuklin, Organic Electronics . 2015,第feba期

机译：基于苯并[1,2-b：3,4-b'：6,5-b“]三噻吩供体和不同受体单元的新型供体-受体（DA）共聚物的合成，光学和电化学性能：作为光伏供体的应用设备
4. Synthesis and Characterization of Trifluoromethylated Benzimidazole and Benzo1,2-B:3,4-B'Dithiophene Based Donor-Acceptor Conjugated Polymer for Polymer Solar Cells [C] . Murali M. G., Arun D. Rao, Praveen C. Ramamurthy Materials Research Society Meeting . 2014

机译：三氟甲基化苯并咪唑和苯并1,2-B：3,4-B'基于聚合物太阳能电池的三噻吩基含量缀合聚合物的合成与表征
5. Synthesis of 1,4-dihydropyrrolo[3,2-b]pyrrole-based organic linkers for metal-organic frameworks [D] . Jalla, Anusha 2015

机译：用于金属-有机骨架的1,4-二氢吡咯并[3,2-b]吡咯基有机连接基的合成
6. All-Small-Molecule Organic Solar Cells Based on a Fluorinated Small Molecule Donor With High Open-Circuit Voltage of 1.07 V [O] . Chunyan Liu, Nailiang Qiu, Yanna Sun, 2020

机译：基于氟化小分子给体的全小分子有机太阳能电池具有1.07 V的高开路电压
7. Oligothiophene-Bridged Bis(arylene ethynylene) small molecules for solution-processible organic solar cells with high open-circuit voltage [O] . Liu Q, Zhan H, Ho CL, 2013

机译：寡噻吩桥联的双（亚芳基乙炔）小分子，用于高开路电压的溶液可加工有机太阳能电池

Novel solution-processible small molecules based on benzo[1,2-b:3,4-b ':5,6-b '']trithiophene for effective organic photovoltaics with high open-circuit voltage

摘要

著录项

相似文献

相关主题

期刊订阅