Unique norbornene based triazole molecule for selective Fe(II) sensing

Bhattacharya Sourav; Shunmugam Raja

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Unique norbornene based triazole molecule for selective Fe(II) sensing

机译：基于独特的降冰片烯基三唑分子用于选择性Fe（II）感测

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A triazole functionalized norbornene monomer (NFTZ) and its corresponding homopolymer (NFTZH) are synthesized. The unique fluorescence properties of the NFTZ molecule are due to the conjugation of two aromatic rings through an amide bond. The chelating behaviour of the NFTZ monomer is explored through the selective binding of Fe(II) in the presence of other metals. The MALDI-TOF analysis and Job's plot clearly confirm the 1 : 2 mode of binding of NFTZ with Fe(II). H-1 NMR and IR spectroscopy clearly confirm the unique amide-iminol tautomerisation.

机译：合成三唑官能化降冰片烯单体（NFTZ）及其相应的均聚物（NFTZH）。 NFTZ分子的独特荧光特性是由于两种芳环的缀合通过酰胺键。通过在其他金属存在下通过Fe（II）的选择性结合来探讨NFTZ单体的螯合行为。 MALDI-TOF分析和作业的剧情明确证明了NFTZ与FE（II）的1：2绑定模式。 H-1 NMR和IR光谱清楚地证实了独特的酰胺 - 氨基醇织物。

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《RSC Advances》 |2015年第91期|共4页
作者
Bhattacharya Sourav; Shunmugam Raja;
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作者单位

Indian Inst Sci Educ &

Res Dept Chem Sci Polymer Res Ctr Kolkata India;

Indian Inst Sci Educ &

Res Dept Chem Sci Polymer Res Ctr Kolkata India;

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正文语种 eng
中图分类化学;
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Unique norbornene based triazole molecule for selective Fe(II) sensing

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