Solution-processable low-bandgap 3-fluorothieno-[3,4-b]thiophene-2-carboxylate-based conjugated polymers for electrochromic applications

Shi Zugui; Neo Wei Teng; Lin Ting Ting; Zhou Hui; Xu Jianwei

首页> 外文期刊>RSC Advances >Solution-processable low-bandgap 3-fluorothieno-[3,4-b]thiophene-2-carboxylate-based conjugated polymers for electrochromic applications

【24h】

Solution-processable low-bandgap 3-fluorothieno-[3,4-b]thiophene-2-carboxylate-based conjugated polymers for electrochromic applications

机译：用于电致变色应用的溶液可加工的低带隙3-氟硫蛋白[3,4-B]噻吩-2-羧酸酯类缀合聚合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

In this paper, a series of low-bandgap donor-acceptor (D-A) conjugated polymers with 3-fluorothieno [3,4-b] thiophene-2-carboxylate (FTT) as an acceptor and ethylenedioxythiophene (EDOT) (P1), acyclic dioxythiophene (AcDOT) (P2) or propylenedioxythiophene (ProDOT) (P3) as donors were synthesized via Stille polymerization. The resultant polymers have good solubility in organic solvents. The polymers were characterized by gel permeation chromatography (GPC), nuclear magnetic resonance spectroscopy (NMR) and thermogravimetric analysis (TGA). Their electrochemical, morphological and electrochromic (EC) properties were investigated, and their absorption-transmission type electrochromic devices (ECDs) were fabricated and characterized. In their neutral states, the polymers displayed deep magenta (P1) to blue (P2, P3) hues, and upon electrochemical oxidation, they revealed grey tones with good optical contrasts (19-37 and 57-58% in visible and near-infrared (NIR) regions, respectively), good coloration efficiencies (158-380 and 279-378 cm(2) C-1 for visible and NIR regions, respectively) and reasonable redox stability (retaining 64-80% original optical contrast after 1000 cycles) under ambient conditions and without any encapsulation of the ECDs.

机译：本文中，一系列低带隙供体 - 受体（DA）与3-氟噻吩[3,4-B]噻吩-2-羧酸酯（FTT）的缀合聚合物作为受体和亚乙二氧噻吩（Edot）（P1），无循环通过STILLE聚合合成作为供体作为供体的二氧噻吩（ACDOT）（P2）或丙二氧基噻吩（P3）。所得聚合物在有机溶剂中具有良好的溶解度。通过凝胶渗透色谱（GPC），核磁共振光谱（NMR）和热重分析（TGA）表征聚合物。研究了它们的电化学，形态学和电致变色（EC）性质，并制备了它们的吸收 - 透射型电致变色装置（ECD）。在它们的中性状态中，聚合物显示深红色（P1）到蓝色（P2，P3）色调，并且在电化学氧化时，它们揭示了具有良好光学对比（19-37和57-58％的灰色色调（19-37和57-58％，可见和近红外）（NIR）区域，分别是良好的着色效率（分别为可见的和裸体区域的158-380和279-378cm（2）C-1）和合理的氧化还原稳定性（在1000次循环后保持64-80％原始光学对比度）在环境条件下，没有任何封装ECD。

著录项

来源
《RSC Advances》 |2015年第117期|共8页
作者
Shi Zugui; Neo Wei Teng; Lin Ting Ting; Zhou Hui; Xu Jianwei;
展开▼
作者单位

ASTAR Inst Mat Res &

Engn Innovis Singapore 138634 Singapore;

ASTAR Inst Mat Res &

Engn Innovis Singapore 138634 Singapore;

ASTAR Inst Mat Res &

Engn Innovis Singapore 138634 Singapore;

ASTAR Inst Mat Res &

Engn Innovis Singapore 138634 Singapore;

ASTAR Inst Mat Res &

Engn Innovis Singapore 138634 Singapore;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Solution-processable low-bandgap 3-fluorothieno-[3,4-b]thiophene-2-carboxylate-based conjugated polymers for electrochromic applications [J] . Shi Zugui, Neo Wei Teng, Lin Ting Ting, RSC Advances . 2015,第117期

机译：用于电致变色应用的溶液可加工的低带隙3-氟硫蛋白[3,4-B]噻吩-2-羧酸酯类缀合聚合物
2. Solution-processable multicolored dithienothiophene-based conjugated polymers for electrochromic applications [J] . Neo W.T., Cho C.M., Song J., European Polymer Journal . 2013,第9期

机译：溶液可加工的彩色二噻吩并噻吩基共轭聚合物，用于电致变色应用
3. Synthesis of Alternating Low-Bandgap Conjugated Polymers Based on Dithieno[2,3-d: 2 ', 3 '- d '] naphtho[1,2-b: 3,4-b '] dithiophene and Enhancement of Photovoltaic Properties with Solvent Additives [J] . Xia Yangjun, Wang Jianlong, Li Jianfeng, Macromolecular chemistry and physics . 2015,第7期

机译：基于二噻吩并[2,3-d：2'，3'-d']萘并[1,2-b：3,4-b']二噻吩的交替低带隙共轭聚合物的合成及溶剂的光电性能增强添加剂类
4. Highly Stable Low Band Gap Conjugated Polymers for Electrochromic Device Applications [C] . Hong Meng, Fred Wudl, Derald Tucker PMSE Symposia . 2002

机译：用于电致变色器件应用的高稳定的低频带隙缀合聚合物
5. π-Conjugated Polymers for Electrochromic and Photovoltaic Applications [D] . Dey, Tanmoy 2010

机译：用于电致变色和光伏应用的π共轭聚合物
6. Synthesis of Isothianaphthene (ITN) and 34-Ethylenedioxy-Thiophene (EDOT)-Based Low-Bandgap Liquid Crystalline Conjugated Polymers [O] . Aohan Wang, Kohsuke Kawabata, Hiromasa Goto 2013

机译：异噻吩并菲（ITN）和34-乙二氧基-噻吩（EDOT）基低带隙液晶共轭聚合物的合成
7. Aromatic Heterocycle 1,3,4-Oxadiazole-Substituted Thieno[3,4-b]thiophene to Build Low-Bandgap Polymer for Photovoltaic Application [O] . Zhu, Dangqiang, Sun, Liang, Liu, Qian, 2015

机译：芳香杂环1,3,4-恶二唑取代噻吩并[3,4-b]噻吩构建低带隙聚合物在光伏领域的应用

Solution-processable low-bandgap 3-fluorothieno-[3,4-b]thiophene-2-carboxylate-based conjugated polymers for electrochromic applications

摘要

著录项

相似文献

相关主题

期刊订阅