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Liquid crystal alignment behavior on sulfonated poly(arylene ether sulfone) films

机译:磺化聚(亚芳基醚砜)膜上的液晶取向行为

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摘要

A series of sulfonated poly(arylene ether sulfone) (PAES#, # is the feed monomer ratio of 3,30-disulfonate-4,4'-dichlorodiphenylsulfone) derivatives were synthesized via nucleophilic addition to investigate the liquid crystal (LC) alignment property of these polymer films. These polymer films exhibited good optical transparency in the visible light region (400-700 nm). For example, the transmittance value (about 96%) of the PAES# film onto a glass substrate at 550 nm is better than that (about 90%) of the polyimide film, the most commonly used LC alignment layer. The LC cells made from the rubbed PAES# films showed a homogeneous planar LC alignment with parallel direction with respect to the rubbing direction. LC cells having pretilt angles from approximately 3 degrees for twisted nematic (TN) to 0 degrees for planar switching mode were obtained from these PAES# films having molar contents of sulfonate groups in the range of 0 to 70 mol%, respectively. The electro-optical characteristics of the LC cells fabricated with the PAES# films such as applying voltage and response time were as good as those fabricated from rubbed polyimide films. We also found that the LC cells made from PAES# films exhibited good thermal stability.
机译:一系列磺化聚(亚芳基醚砜)(Paes#,#是3,30-二磺酸-4,4'-二氯二苯基砜)衍生物的衍生物通过亲核外加入来研究液晶(LC)对准性能这些聚合物膜。这些聚合物膜在可见光区域(400-700nm)中表现出良好的光学透明性。例如,在550nm处的Paes#膜的透射值(约96%)在玻璃基板上优于聚酰亚胺膜的(约90%),最常用的LC取向层。由摩擦的PAES#薄膜制成的LC电池显示出相对于摩擦方向的平行方向的均匀平面LC对准。从这些PAES#薄膜的磺酸盐基团的摩尔含量分别在0至70摩尔%的范围内,获得具有从大约3度的扭曲向列(TN)至0度的预扭曲向量(TN)至0度的预倾角为0度。用PAES#薄膜制造的LC电池的电光特性与施加电压和响应时间一样好,与由摩擦聚酰亚胺膜制成的那些。我们还发现,由Paes#薄膜制成的LC电池表现出良好的热稳定性。

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  • 来源
    《RSC Advances》 |2015年第79期|共6页
  • 作者单位

    Dong A Univ Dept Chem Engn Busan 604714 South Korea;

    Seoul Natl Univ Sch Chem &

    Biol Engn Seoul 151742 South Korea;

    Soongsil Univ Dept Elect Engn Seoul 156743 South Korea;

    Seoul Natl Univ Sch Chem &

    Biol Engn Seoul 151742 South Korea;

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  • 正文语种 eng
  • 中图分类 化学;
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