Redetermination of the crystal structures of the 'Arppe compound' Bi24O31Cl10 and the isomorphous Bi24O31Br10

Eggenweiler U.; Kramer V.; Keller E.

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Redetermination of the crystal structures of the 'Arppe compound' Bi24O31Cl10 and the isomorphous Bi24O31Br10

机译：重新确定“ Arppe化合物” Bi24O31Cl10和同构的Bi24O31Br10的晶体结构

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The crystal structures of Bi24O31X10 (X = Cl, Br; 24-bismuth 31-oxide decachloride/-bromide) have been redetermined. The structure models obtained resemble the model described in the literature about 60 years ago, but differ from it in some details of the O substructure and in the fact that the structure for X = Cl is a twofold superstructure of the literature model. A fictional mechanism is given by which the formerly described incorrect O substructure is transferred into the correct one. [References: 17]

机译：Bi24O31X10的晶体结构（X = Cl，Br; 24-铋31氧化物十氯化物/溴化物）已重新确定。所获得的结构模型类似于大约60年前文献中描述的模型，但是在O子结构的某些细节以及X = Cl的结构是文献模型的双重上层结构这一事实上有所不同。给出了一种虚构的机制，通过该机制可以将先前描述的不正确的O子结构转换为正确的O子结构。 [参考：17]

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《Acta Crystallographica, Section B. Structural Science》 |2000年第3期|共7页
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Eggenweiler U.; Kramer V.; Keller E.;
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中图分类晶体学;
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1. Redetermination of the crystal structures of the 'Arppe compound' Bi24O31Cl10 and the isomorphous Bi24O31Br10 [J] . Eggenweiler U., Kramer V., Keller E. Acta Crystallographica, Section B. Structural Science . 2000,第3期

机译：重新确定“ Arppe化合物” Bi24O31Cl10和同构的Bi24O31Br10的晶体结构
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Redetermination of the crystal structures of the 'Arppe compound' Bi24O31Cl10 and the isomorphous Bi24O31Br10

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