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首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >X-ray studies on crystalline complexes involving amino acids and peptides. XXXVII. Novel aggregation patterns and effect of chirality in the complexes of DL- and L-lysine with glutaric acid.
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X-ray studies on crystalline complexes involving amino acids and peptides. XXXVII. Novel aggregation patterns and effect of chirality in the complexes of DL- and L-lysine with glutaric acid.

机译:对涉及氨基酸和肽的晶体复合物进行X射线研究。 XXXVII。 DL-和L-赖氨酸与戊二酸配合物的新型聚集模式和手性效应。

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The complexes of glutaric acid with DL-lysine contain singly positively charged zwitterionic lysinium ions and singly negatively charged semi-glutarate ions. Both the ions exhibit different conformations in the two complexes. The structures contain head-to-tail sequences of amino acids. However, the aggregation patterns in the two complexes are entirely different, demonstrating the effect of chirality on molecular aggregation. These patterns also turn out to be different from those so far observed, in structures containing amino acids. The structures contain characteristic interaction patterns involving linear arrays of alternating amino and carboxylate groups.
机译:戊二酸与DL-赖氨酸的络合物包含带正电的两性离子的赖氨酸离子和带负电的半戊二酸离子。两种离子在两种络合物中均显示出不同的构象。该结构包含氨基酸的从头到尾的序列。然而,两种复合物中的聚集模式完全不同,证明了手性对分子聚集的影响。在包含氨基酸的结构中,这些模式也与迄今为止观察到的模式不同。该结构包含涉及交替的氨基和羧酸酯基团的线性阵列的特征相互作用模式。

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