Structure of a new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, from high-resolution synchrotron powder diffraction data

Orosel D.; Dinnebier R.E.; Blatov V.A.; Jansen M.

首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >Structure of a new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, from high-resolution synchrotron powder diffraction data

【24h】

Structure of a new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, from high-resolution synchrotron powder diffraction data

机译：基于高分辨率同步加速器粉末衍射数据的新型高温高压氧化锑（γ-Sb_2O _3）的结构

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A quenchable new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, has been obtained at hydrostatic pressures of 9-11 GPa and temperatures of 573-773 K. Its crystal structure has been determined from high-resolution synchrotron powder diffraction data. γ-Sb _2O _3 consists of three-dimensionally cross-linked infinite chains of SbO _3E units (E = lone pair) with the chains forming tetragonal rod-packing. The underlying topology of γ-Sb _2O _3 (3,3T8) is found very rarely in inorganic structures; it is realised only for the polyanion [Si _4O _4N _6] ~(10-) that occurs in the Ce _4(Si _4O _4N _6)O structure type. The structural relation to the two previously known polymorphs of Sb _2O _3 at ambient pressure, valentinite and senarmontite is discussed.

机译：在9-11 GPa的静水压力和573-773 K的温度下，获得了可淬火的新型氧化锑（III）高压-高温改性剂γ-Sb_2O _3。其晶体结构由高分辨率同步加速器粉末衍射数据。 γ-Sb_2O _3由SbO _3E单元（E =孤对）的三维交联无限链组成，这些链形成四方杆堆积。 γ-Sb_2O _3（3,3T8）的基本拓扑在无机结构中很少见;仅对于在Ce _4（Si _4O _4N _4N _6N）O结构类型中出现的聚阴离子[Si _4O _4N _6]〜（10-）实现。讨论了在环境压力下与Sb _2O _3的两个先前已知的多晶型物，白铁矿和硒酸钠的结构关系。

著录项

来源
《Acta Crystallographica, Section B. Structural Science》 |2012年第1期|共7页
作者
Orosel D.; Dinnebier R.E.; Blatov V.A.; Jansen M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
3; 3T8 topology; antimony(III) oxide; high-pressure-high-temperature synthesis; powder diffraction;

机译：3;3T8拓扑结构;三氧化二锑;高温高压合成;粉末衍射;

相似文献

外文文献
中文文献
专利

1. Structure of a new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, from high-resolution synchrotron powder diffraction data [J] . Orosel D., Dinnebier R.E., Blatov V.A., Acta Crystallographica, Section B. Structural Science . 2012,第1期

机译：基于高分辨率同步加速器粉末衍射数据的新型高温高压氧化锑（γ-Sb_2O _3）的结构
2. Antimony(III) tellurium(IV) chloride trioxide SbTeO3Cl: synthesis and ab initio structure determination from X-ray and neutron powder diffraction data [J] . Alonso JA. Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 1998,第12期

机译：三氧化二锑碲（IV）SbTeO3Cl：从X射线和中子粉末衍射数据确定合成和从头算结构
3. Structure refinements of the layered intergrowth phases Sb(III)Sb(x)(V)A(1-x)TiO(6) (x similar or equal to 0, A = Ta, Nb) using synchrotron X-ray powder diffraction data [J] . Ling CD, Thompson JG, Schmid S, Acta Crystallographica, Section B. Structural Science . 1997,第6期

机译：使用同步加速器X射线粉末衍射数据细化层状共生相Sb（III）Sb（x）（V）A（1-x）TiO（6）（x等于或等于0，A = Ta，Nb）的结构
4. Ab Initio Determination of a New Complex Structure (55 Non-Hydrogen Atoms) from Synchrotron Powder Data: An Uncommon Nickel Succinate, Ni{sub}7(C{sub}4H{sub}4O{sub}4){sub}4(OH){sub}6(H{sub}2O){sub}3·7H{sub}2O [C] . N. Guillou, C. Livage, W. van Beek, European Powder Diffraction Conference . 2004

机译：AB初始测定来自同步粉末数据的新复杂结构（55个非氢原子）：罕见的镍琥珀酸盐，Ni {sub} 7（c {sub} 4h} 4）{sub} 4（哦）{sub} 6（h {sub} 2o）{sub} 3·7h {sub} 2o
5. Beyond FIT2D: Calculating Intensity Errors for Data Analysis of X-Ray Synchrotron Powder Diffraction Data. [D] . Sims, Melissa. 2014

机译：超越FIT2D：计算X射线同步加速器粉末衍射数据数据分析的强度误差。
6. The crystal structures of tetrakis(μ-n-butyrato-κ2O:O′)bisbromidorhenium(III) and tetrakis(μ-n-butyrato-κ2O:O′)bischloridorhenium(III) acetonitrile disolvate [O] . Carly R. Reed, William W. Brennessel 2015

机译：四（μ-n-butyrato-κ2）的晶体结构O：O）bis bromidorhenium（III）和tetrakis（μ-n-butyrato-κ2O：O）双氯化（III）乙腈二溶剂化物
7. The formation and stability of molybdenum-antimony and tungsten-antimony ternary oxides Sb 2MO 6, Sb 2M 2O 9, Sb 2Mo 3O 12 and Sb 4MO 9 in the gas phase (M = Mo, W). Quantum chemical and mass spectrometric studies [O] . Berezovskaya E., Milke E., Binnewies M. 2012

机译：钼-锑和钨-锑三元氧化物Sb 2MO 6，Sb 2M 2O 9，Sb 2Mo 3O 12和Sb 4MO 9在气相中的形成和稳定性。量子化学和质谱研究
8. Synthesis and Characterization of Tert-Butylgallium-Antimony Compounds; X-RayCrystal Structures of t-Bu3GaSb(SiMe3)3, t-Bu2GaSb(SiMe3)2, and t-Bu2GaSb(SiMe3)Ga(t-Bu)2Cl, The First Example of a Gallium-Antimony Mixed-Bridge Compound [R] . Wells, R. L., Foos, E. E., White, P. S., 1997

机译：叔丁基镓 - 锑化合物的合成与表征; t-Bu3Gasb（sime3）3，t-Bu2Gasb（sime3）2和t-Bu2Gasb（sime3）Ga（t-Bu）2Cl的X射线晶体结构，镓 - 锑混合桥化合物的第一个例子

Structure of a new high-pressure-high-temperature modification of antimony(III) oxide, γ-Sb _2O _3, from high-resolution synchrotron powder diffraction data

摘要

著录项

相似文献

相关主题

期刊订阅