On the structural relations of malachite. II. the brochantite MDO polytypes

Girgsdies F.; Behrens M.

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On the structural relations of malachite. II. the brochantite MDO polytypes

机译：关于孔雀石的结构关系。二。褐铁矿MDO多型

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The structural relation between malachite and the brochantite MDO (maximum degree of order) polytypes is discussed. It is demonstrated that the same building blocks which form the basis of brochantite polytypism also occur in malachite. The different arrangements of these building blocks in the two mineral structures are rationalized as a result of the different coordination geometries required by the respective non-metal atoms acting as linkers. The compound stoichiometries are discussed in light of a common structured formula scheme, in which pairs of H atoms can play a similar role as single non-H atoms. An overview on the occurrence of malachite-like building blocks in several other crystal structures is given.

机译：讨论了孔雀石和青铜矿MDO（最大有序度）多型之间的结构关系。已证明，孔雀石中也出现了构成青铜矿多型性基础的相同结构单元。由于相应的非金属原子作为连接基团需要不同的配位几何结构，因此使两种矿物结构中这些构件的不同排列合理化。根据常见的结构式方案讨论化合物的化学计量，其中成对的H原子可起与单个非H原子相似的作用。概述了孔雀石状结构单元在其他几种晶体结构中的存在。

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《Acta Crystallographica, Section B. Structural Science》 |2012年第6期|共7页
作者
Girgsdies F.; Behrens M.;
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正文语种 eng
中图分类晶体学;
关键词
brochantite; carbonates; copper minerals; malachite; structure relations; sulfates;

机译：褐铁矿;碳酸盐;铜矿物;孔雀石;结构关系;硫酸盐;

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1. On the structural relations of malachite. II. the brochantite MDO polytypes [J] . Girgsdies F., Behrens M. Acta Crystallographica, Section B. Structural Science . 2012,第6期

机译：关于孔雀石的结构关系。二。褐铁矿MDO多型
2. Discreditation of "orthobrochantite" (IMA 78-64) as the MDO _1 polytype of brochantite [J] . Mills S.J., Kampf A.R., Pasero M., European journal of mineralogy . 2010,第3期

机译：辨别“正方晶石”（IMA 78-64）为MDO _1多晶型的
3. On the structural relations of malachite. I. the rosasite and ludwigite structure families [J] . Girgsdies F., Behrens M. Acta Crystallographica, Section B. Structural Science . 2012,第2期

机译：关于孔雀石的结构关系。 I.蔷薇石和路德维希岩结构族
4. EVALUATION OF MICROSTRUCTURAL DAMAGE AND ALTERATION OF POLYTYPES TO DETERMINE THE AGING OF SILICON CARBIDE [C] . T. W. Koenig, L. Meshi, Z. Foxman, Annual Review of Progress in Quantitative Nondestructive Evaluation . 2014

机译：评价微观结构损伤及多晶硅改变，确定碳化硅老化
5. Polytype stability, microstructural evolution, and impurities at the interface of homoepitaxial 4H-silicon carbide(1120) thin films grown via hot-wall chemical vapor deposition [D] . Bishop, Seann M. G. 2006

机译：通过热壁化学气相沉积法生长的同质外延4H-碳化硅（1120）薄膜的界面上的多型稳定性，微观结构演变和杂质
6. Studies on the poll glands of the one-humped camel in relation to reproductive activity. II. Ultrastructural observations. [O] . M D Tingari, M A George 1984

机译：关于驼峰骆驼的生殖腺的研究。二。超微结构观察。
7. On the structural relations of malachite. II. The brochantite MDO polytypes [O] . Girgsdies, F., Behrens, M. 2012

机译：论孔雀石的结构关系。 II。 Brochantite mDO多型
8. Polytype Distribution in Presolar SiC: Microstructural Characterization by Transmission Electron Microscopy. [R] . Daulton, T. L., Lewis, R. S., Amari, S. 2001

机译：预制siC中的多型分布：透射电子显微镜的微观结构表征。

On the structural relations of malachite. II. the brochantite MDO polytypes

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