[MPh4][BPh4], M = P, As and Sb

Lloyd MA; Brock CP

首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >[MPh4][BPh4], M = P, As and Sb

【24h】

[MPh4][BPh4], M = P, As and Sb

机译：[MPh4] [BPh4]，M = P，As和Sb

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The structures of [MPh4][BPh4], M = P, As and Sb, crystallize in a superstructure (I (4) over bar, Z' = 1/2) of the P (4) over bar 2(1)c, Z' = 1/4, structure known for MPh4, M = C, Si, Ge, Sn and Pb. The arrangement of the ions is the same as for CaWO4 (scheelite; I4(1)/a, Z' = 1/4), which is typical of many other ionic XYO4 structures. Crystals of [MPh4][BPh4] turn a pinkish amber when exposed to UV light; ESR spectra confirm that free radicals are generated.

机译：[MPh4] [BPh4]的结构，M = P，As和Sb，在2（1）c上方P（4）的上层结构（I（4）在条形上方，Z'= 1/2）中结晶。，Z′＝ 1/4，对于MPh 4已知的结构，M ＝ C，Si，Ge，Sn和Pb。离子的排列与CaWO4相同（白钨矿; I4（1）/ a，Z'= 1/4），这是许多其他离子XYO4结构的典型特征。 [MPh4] [BPh4]的晶体在紫外线照射下会变成粉红色的琥珀色; ESR光谱证实产生了自由基。

著录项

来源
《Acta Crystallographica, Section B. Structural Science》 |1997年第5期|共7页
作者
Lloyd MA; Brock CP;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
CRYSTAL-STRUCTURE; MOLECULAR-STRUCTURES; BOND LENGTHS; X-RAY; REDETERMINATION; TETRAPHENYLTIN; CHEMISTRY;

机译：晶体结构;分子结构;键长;X射线;重测定;四苯甲基;化学;

相似文献

外文文献
中文文献
专利

1. [MPh4][BPh4], M = P, As and Sb [J] . Lloyd MA, Brock CP Acta Crystallographica, Section B. Structural Science . 1997,第5期

机译：[MPh4] [BPh4]，M = P，As和Sb
2. Synthesis and Structural Studies of Tetrahedral [M(Ph2P(CH=CH)PPh2)2]BPh4 and [M(Ph2P(CH2)_nPPh2)2]BPh4 (n = 2, 3) Complexes for M = Copper(I), Silver(I), and Gold(I) [J] . Peter C. Healy, Bradley T. Loughrey, Michael L. Williams Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2012,第7期

机译：四面体[M（Ph2P（CH = CH）PPh2）2] BPh4和[M（Ph2P（CH2）_nPPh2）2] BPh4（n = 2，3）配合物的合成和结构研究，M =铜（I），银（I）和金币（I）
3. Nitrile exchange reactions of [WI(CO)(NCMe){P((OPr)-Pr-i)(3)}(2)(eta(2)-MeC2Me)][BPh4]; X-ray crystal structures of [WI(CO)(L){P((OPr)-Pr-i)(3)}(2)(eta(2)-MeC2Me)][BPh4] {L = (NCPr)-Pr-i, (NCBu)-Bu-t, NCCH2Ph, 1,2-C6H4(NCCH2)(2)} [J] . Baker PK., Drew MGB., Moore DS. Journal of Organometallic Chemistry . 2002,第1a2期

机译：[WI（CO）（NCMe）{P（（OPr）-Pr-i）（3）}（2）（eta（2）-MeC2Me）] [BPh4]的腈交换反应; [WI（CO）（L）{P（（OPr）-Pr-i）（3）}（2）（eta（2）-MeC2Me）] [BPh4]的X射线晶体结构{L =（NCPr） -Pr-i，（NCBu）-Bu-t，NCCH2Ph，1,2-C6H4（NCCH2）（2）}
4. Synthesis, protonation and x-ray crystal structures of Ni(SC_6H_3Me_2-2,6){triphos}BPh_4 and Ni(SC_6H_4R-2){triphos}BPh4 {R = Me, MeO Or Cl; triphos = PhP(Ph_2PCH_2CH_2)_2}: Unusual structure when R = Cl [C] . Thaer M. M. Al-Rammahi, William Clegg, Michael Probert, International Conference on Applied Science and Technology . 2019

机译：ni（sc_6h_3me_2-2,6）{triphos} bph_4和ni（sc_6h_4r-2）{triphos} bph4 {r = me，meo或cl的合成，质子化和X射线晶体结构; triphos = php（ph_2pch_2ch_2）_2}：当r = cl时异常结构
5. The Feasibility of Over-Summer Snow Storage at the Craftsbury Outdoor Center, Craftsbury VT [D] . Weiss, Hannah. 2021

机译：Craftsbury户外中心的过度夏季雪储存的可行性，Craftsbury VT
6. Total structure determination of surface doping Ag46Au24(SR)32(BPh4)2 nanocluster and its structure-related catalytic property [O] . Shuxin Wang, Shan Jin, Sha Yang, 2015

机译：表面掺杂Ag46Au24（SR）32（BPh4）2纳米簇的总结构测定及其结构相关的催化性能
7. Reactions of the organoplatinum complex Pt(cod) (neoSi)Cl (neoSi = trimethylsilylmethyl) with the non-coordinating anions SbF6– and BPh4– [O] . Michael Neugebauer, Simon Schmitz, Maren Krause, 2018

机译：有机铂络合物Pt（鳕鱼）（Neosi）（Neosi =三甲基甲硅烷基甲基）与非配位阴离子SBF6-和BPH4-的反应
8. Detailed design data package: 3.1a-Film cooler pressure drop data; Item 3.2a - SBS packing selection; Item 3.2b, 3.2c - Pressure drop data for SBS distribution plate; and Item 3.2e - SBS distribution plate and liquid risers. PHTD pilot-scale melter testing system cost account milesonte 1.2.2.04.15A [R] . Whyatt, G. A., Anderson, L. D., Evans, J. 1996

机译：详细设计数据包：3.1a-薄膜冷却器压降数据;项目3.2a - sBs包装选择;项目3.2b，3.2c - sBs分配板的压降数据;和项目3.2e - sBs分配板和液体提升管。 pHTD中试规模熔化器测试系统成本账户里程为1.2.2.04.15a

[MPh4][BPh4], M = P, As and Sb

摘要

著录项

相似文献

相关主题

期刊订阅