Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization

Jeffrey A. Rood; Ashley L. Huttenstine; Zachery A. Schmidt; Michael R. White; Allen G. Oliver

首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization

【24h】

Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization

机译：线性碱土金属次膦酸酯配位聚合物：合成与结构表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Reaction of alkaline earth metal salts with diphenylphosphinic acid in dimethylformamide solvent afforded four coordination polymers: [Mg_3(O_2PPh_2)_6(DMF)_2]·2DMF (I), [Ca(O_2PPh_2)_2-(DMF)_2] (II), [Sr(O_2PPh_2)_2(DMF)_2] (III) and [Ba(O_2PPh_2)_2-(DMF)_2] (IV) (where DMF is N,N-dimethylformamide). Single-crystal X-ray diffraction revealed that all four compounds produce linear chain structures in the solid state, with the Ca, Sr and Ba forming isostructural crystals. The bulk materials were characterized by FT-IR and ~1H NMR spectroscopy and elemental analyses.

机译：碱土金属盐与二苯基次膦酸在二甲基甲酰胺溶剂中的反应得到四种配位聚合物：[Mg_3（O_2PPh_2）_6（DMF）_2]·2DMF（I），[Ca（O_2PPh_2）_2-（DMF）_2]（II）， [Sr（O_2PPh_2）_2（DMF）_2]（III）和[Ba（O_2PPh_2）_2-（DMF）_2]（IV）（其中DMF为N，N-二甲基甲酰胺）。 X射线单晶衍射表明，所有四种化合物均在固态下产生线性链结构，而Ca，Sr和Ba形成同构晶体。块状材料通过FT-IR和〜1H NMR光谱及元素分析进行表征。

著录项

来源
《Acta Crystallographica, Section B. Structural Science》 |2014年第3期|共6页
作者
Jeffrey A. Rood; Ashley L. Huttenstine; Zachery A. Schmidt; Michael R. White; Allen G. Oliver;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Linear; alkaline; synthesis;

机译：线性;碱性;合成;

相似文献

外文文献
中文文献
专利

1. Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization [J] . Jeffrey A. Rood, Ashley L. Huttenstine, Zachery A. Schmidt, Acta Crystallographica, Section B. Structural Science . 2014,第3期

机译：线性碱土金属次膦酸酯配位聚合物：合成与结构表征
2. Structural diversity controlled by alkali/alkaline earth metals for heterometallic Ae(I)/Ae(II)-Zn-II coordination polymers based on 4-nitrobenzene-1,2-dicarboxylate [J] . Zhu Wen-Gang, Zheng Yue-Qing, Zhu Hong-Lin, Journal of Coordination Chemistry . 2016,第19a20期

机译：由碱/碱土金属控制的基于4-硝基苯-1,2-二羧酸酯的杂金属Ae（I）/ Ae（II）-Zn-II配位聚合物的结构多样性
3. Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II) [J] . Gholivand Khodayar, Fallah Nasrin, Valmoozi Ali Asghar Ebrahimi, Journal of Molecular Structure . 2020,第1期

机译：锡（IV）和铜（II）膦酸盐配位聚合物的合成与结构表征
4. Synthesis and Structural Consideration of Metal-Organic Framework (MOF) Coordination Polymer with Various Metal Linker Ratios [C] . Halina Misran, Atiah Mohd Aminuddin, Faizul Akmal Mohd Zini International Conference on Fracture and Strength of Solids . 2011

机译：金属有机骨架（MOF）配位聚合物的合成与结构考虑，具有各种金属连接率
5. Coordination polymers of the alkaline earth metals for applications in synthesis and gas storage. [D] . Rosado Flores, Peter Josue. 2014

机译：碱土金属的配位聚合物，用于合成和气体存储。
6. Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the Mn6(μ4-O)210+ Unit [O] . Eleni E. Moushi, Anastasios J. Tasiopoulos, Manolis J. Manos 2010

机译：基于Mn6（μ）的金属团簇和配位聚合物的合成与结构表征4-O）2 10+单元
7. Synthesis of monomeric and polymeric alkali and alkaline earth metal complexes using a phosphinoselenoic amide ligand in metal coordination sphere [O] . Bhattacharjee J, Kottalanka R K, Adimulam H, 2014

机译：在金属配位域中使用膦硒烯酰胺配体合成单体和聚合的碱金属和碱土金属配合物
8. Organometallic Nonlinear Optical (NLO) Polymers. 2. Synthesis of Main-Chain Organometallic Polymers and a Structural Study of Ferrocene NLO-Phores. [R] . Wright, M. E., Toplikar, E. G. 1992

机译：有机金属非线性光学（NLO）聚合物。 2.主链有机金属聚合物的合成和二茂铁NLO-孔的结构研究。

Linear alkaline earth metal phosphinate coordination polymers: synthesis and structural characterization

摘要

著录项

相似文献

相关主题

期刊订阅