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首页> 外文期刊>Acta Crystallographica, Section B. Structural science, crystal engineering and materials >Unique thermodynamic relationships for ?_fH~o and ?_fG~o for crystalline inorganic salts. I. Predicting the possible existence and synthesis of Na_2SO_2 and Na_2SeO_2. Addendum
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Unique thermodynamic relationships for ?_fH~o and ?_fG~o for crystalline inorganic salts. I. Predicting the possible existence and synthesis of Na_2SO_2 and Na_2SeO_2. Addendum

机译:结晶无机盐的Δ_fH_o和Δ_fG_o具有独特的热力学关系。 I.预测Na_2SO_2和Na_2SeO_2的可能存在和合成。附录

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Our article (Vegas et al., 2012) reported, inter alia, the likely stability of the SO_2~(2-) moiety in the solid state in its compounds. Our conclusions were that K_2SO_2 and Cs_2SO_2 emerged as the two most likely alkali metal sulfoxylates to be stable and that Na_2SeO_2 was the more suitable sulfoxylate to be targeted for synthesis. Since our article appeared we have received an email from Sergei V. Makarov (University of Ivanovo, Russia) drawing our attention to his earlier work (Svarovsky et al., 2000; Makarov et al., 2012a,b) which we had not been aware of. His work reports that he has observed the SO_2~(2-) anion, in aqueous solution.
机译:我们的文章(Vegas等,2012)报告了SO_2〜(2-)部分在其化合物中处于固态的可能稳定性。我们的结论是,K_2SO_2和Cs_2SO_2是最可能稳定的两种碱金属亚硫酸盐,而Na_2SeO_2是最适合合成的亚硫酸盐。自从我们的文章发表以来,我们收到了来自Sergei V. Makarov(俄罗斯伊万诺沃大学)的电子邮件,提醒我们注意他的早期工作(Svarovsky等,2000; Makarov等,2012a,b),但我们从未意识到。他的工作报告说他已经观察到了水溶液中的SO_2〜(2-)阴离子。

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