A new three-dimensional anionic cadmium(II) dicyanamide network

Qiang Li; Hui-Ting Wang

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A new three-dimensional anionic cadmium(II) dicyanamide network

机译：一个新的三维阴离子镉（II）双氰胺网络

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A new cadmium dicyanamide complex, poly[tetramethylphosphonium [μ-chlorido-di-μ-dicyanamido-κ4N1:N5-cadmium(II)]], [(CH3)4P][Cd(NCNCN)2Cl], was synthesized by the reaction of tetramethylphosphonium chloride, cadmium nitrate tetrahydrate and sodium dicyanamide in aqueous solution. In the crystal structure, each CdII atom is octahedrally coordinated by four terminal N atoms from four anionic dicyanamide (dca) ligands and by two chloride ligands. The dicyanamide ligands play two different roles in the building up of the structure; one role results in the formation of [Cd(dca)Cl]2 building blocks, while the other links the building blocks into a three-dimensional structure. The anionic framework exhibits a solvent-accessible void of 673.8??3, amounting to 47.44% of the total unit-cell volume. The cavities in the network are occupied by pairs of tetramethylphosphonium cations.

机译：通过反应合成了一种新型的双氰胺镉络合物聚[四甲基phosph [μ-氯代-二-μ-二氰基氨基-κ4N1：N5-镉（II）]] [[CH3）4P] [Cd（NCNCN）2Cl]。水溶液中加入四甲基氯化chloride，硝酸镉四水合物和双氰胺钠。在晶体结构中，每个CdII原子由来自四个阴离子双氰胺（dca）配体的四个末端N原子和两个氯化物配体八面体配位。双氰胺配体在结构的建立中起着两种不同的作用。一种作用导致形成[Cd（dca）Cl] 2结构单元，而另一种则将结构单元链接成三维结构。阴离子骨架的溶剂可及孔隙为673.8？3 3，占单位晶胞总体积的47.44％。网络中的空腔被成对的四甲基phosph阳离子占据。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第11期|共3页
作者
Qiang Li; Hui-Ting Wang;
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正文语种 eng
中图分类晶体学;
关键词
crystal structure; dicyanamide; three-dimensional coordination polymer; tetramethylphosphonium; metal–organic polymeric networks;

机译：晶体结构;双氰胺;三维配位聚合物;四甲基phosph;金属有机聚合物网络;

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1. A three-dimensional anionic metal–dicyanamide network in poly[ethyltriphenylphosphonium [tri-μ2-dicyanamidato-cadmium(II)]] [J] . Qiang Li Acta crystallographica. Section C, Structural chemistry. . 2015,第1期

机译：聚[乙基三苯基phosph [tri-μ2-dicyanamidato-镉（II）]]中的三维阴离子金属-双氰胺网络
2. A novel (2,3,5)-connected double interpenetrating three-dimensional network cadmium coordination polymer with flexible tri(triazole) and dicyanamide ligands [J] . Haiyan Li, Haipeng Wang, Hongliang Wang Inorganic Chemistry Communications . 2011,第1期

机译：具有柔性三（三唑）和双氰胺配体的新型（2,3,5）连接的双互穿三维网络镉配位聚合物
3. Construction of a three‐dimensional supramolecular framework based on an anionic cadmium(II) coordination network and protonated dipyridine organic cations [J] . Zhou Qian-Kun, Wang Lin, Liu Dong Acta crystallographica. Section C, Structural chemistry. . 2018,第8期

机译：基于阴离子镉（II）配位网络和质子二吡啶有机阳离子的三维超分子框架的构建
4. Syntheses and Crystal Structures of a Series of Cadmium(Ⅱ) Coordination Polymers withEnd-to-end Dicyanamide Bridges [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：一系列具有端到端双氰胺桥的镉（Ⅱ）配位聚合物的合成和晶体结构
5. THE INFLUENCE OF FULVIC ACID ON COPPER(II), CADMIUM(II) AND ZINC(II) REMOVAL FROM DRINKING WATER BY ALUM COAGULATION AND COPPER(II) AND CADMIUM(II) COMPLEXING CAPACITY MEASUREMENTS OF FULVIC ACID AND NATURAL FRESHWATER SAMPLES BY DIALYSIS TITRATION [D] . TRUITT, RALPH EDWARD. 1980

机译：褐藻酸对氧化铝凝结去除饮用水中铜（II），镉（II）和锌（II）的影响以及通过透析滴定铜（II）和镉（II）的络合容量测量及天然淡水样品
6. A chiral three-dimensional network in polyμ-44′-bipyridine-di-μ-formato-cadmium(II) [O] . Li Zhao, Jian-Li Lin, Wei Xu, 2009

机译：聚μ-44-联吡啶-di-μ-格式镉（II）中的手性三维网络
7. A chiral three-dimensional network in poly[μ-4,4′-bipyridine-di-μ-formato-cadmium(II)] [O] . Zhao, Li, Lin, Jian-Li, Xu, Wei, 2009

机译：聚[μ-4,4'-联吡啶-di-μ-格式镉（II）]中的手性三维网络

A new three-dimensional anionic cadmium(II) dicyanamide network

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