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首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >Dendocarbin A: a sesquiterpene lactone from Drimys winteri
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Dendocarbin A: a sesquiterpene lactone from Drimys winteri

机译:Dendocarbin A:Drimys winteri的倍半萜内酯

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摘要

The natural compound dendocarbin A, C15H22O3, is a sesquiterpene lactone isolated for the first time from Drimys winteri for var chilensis. The compound crystallizes in the orthorhombic space group P212121 and its X-ray crystal structure confirmed the S/R character of the chiral centres at C-5/C-10 and C-9/C-11, respectively. The α-OH group at C-11 was found to be involved in intermolecular hydrogen bonding, defining chains along the <100> 21 screw axis.
机译:天然的化合物dendocarbin A,C15H22O3,是一种倍半萜烯内酯,是首次从Drimys winteri分离得到的。该化合物在正交晶空间群P212121中结晶,其X射线晶体结构分别证实了C-5 / C-10和C-9 / C-11上手性中心的S / R特性。发现C-11处的α-OH基团参与分子间氢键结合,从而定义了沿<100> 21螺旋轴的链。

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